Lot numbers can be found on the outside label of a product:
(S)-2-((tert-Butoxycarbonyl)amino)-6-hydroxyhexanoic acid
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CAS No. 77611-37-1
- Cat. No. CS-0179118
- Purity≥97%
- MDL No.None
*For research and further manufacturing use only, not for direct human use.
Structure of 77611-37-1
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General Information
- CAS No. 77611-37-1
- Cat. No. CS-0179118
- Purity ≥97%
- MDL No. None
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₁H₂₁NO₅
- Molecular Weight 247.29
- Synonym(s) Boc-L-6-hydroxynorleucine
- SMILES CC(C)(OC(N[C@H](C(O)=O)CCCCO)=O)C
Description
This chiral building block features a protected amine and a hydroxyl group flanking a six-carbon chain, enabling direct incorporation into peptide architectures. The tert-butyl carbamate handle ensures orthogonal deprotection, while the pendant hydroxy function offers a site for selective derivatization or glycosylation.
Application
(S)-2-((tert-Butoxycarbonyl)amino)-6-hydroxyhexanoic acid serves as a versatile chiral building block for peptide and heterocyclic synthesis, enabling efficient access to bioactive scaffolds. The protected amine and terminal hydroxyl group provide orthogonal functionality for sequential derivatization, while the tert-butoxycarbonyl (Boc) group ensures bench stability and compatibility with standard coupling protocols. Its structure facilitates straightforward purification and integration into multi-step syntheses of complex molecules.
Synthesis
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Route1
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In-stock
77302-72-8 - ~67%
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In-stock
77611-37-1
References
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Matsumoto, Naoki; Kaneko, Katsura; Nagai, Hazuki; Konuki, Kaname; Tsuchida, Toshio; Issiki, Kunio Patent: US2004/249205 A1, 2004 ; Location in patent: Page 3 ;
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References
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Rumsh; Mikhailova; Mikhura; Prudchenko; Chikin; Mikhaleva; Kaliberda; Dergousova; Mel'Nikov; Formanovskii Russian Journal of Bioorganic Chemistry, 2008 , vol. 34, # 6 p. 660 - 667
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Route3
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In-stock
24424-99-5 - ~79%
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In-stock
77611-37-1
References
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Keystone Biomedical, Inc. Patent: US6335443 B1, 2002 ; Location in patent: Page column 8 ;
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 95.86
- LogP 1.1269
- H_Acceptors 4
- H_Donors 3
- Rotatable_Bonds 6
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Key Words
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