2'-Bromo-2,6-dimethoxy-1,1'-biphenyl

Name: 2'-Bromo-2,6-dimethoxy-1,1'-biphenyl
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 755017-61-9
Cat. No. CS-0194949
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2'-Bromo-2,6-dimethoxy-1,1'-biphenyl|CS-0194949

Structure of 755017-61-9

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Description

This brominated biphenyl features a 2'-bromo substituent flanked by two methoxy groups at the 2 and 6 positions, enhancing its electron-rich character and stability under standard conditions. The ortho-methoxy groups provide steric protection to the bromine site, enabling selective cross-coupling reactions in synthetic sequences.

Application

2'-Bromo-2,6-dimethoxy-1,1'-biphenyl serves as a versatile building block in cross-coupling reactions, enabling efficient construction of biaryl scaffolds under palladium-catalyzed conditions. The ortho-methoxy groups provide steric and electronic modulation, enhancing regioselectivity and stability during synthesis. Its bench-stable nature and compatibility with diverse functional groups make it well-suited for iterative coupling strategies in medicinal chemistry and materials science applications.

General Information

CAS No. 755017-61-9
Cat. No. CS-0194949
Purity ≥98%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₄H₁₃BrO₂
Molecular Weight 293.16
Synonym(s) 2',6'-dimethoxy-2-biphenylbromide
SMILES COC1=C(C2=CC=CC=C2Br)C(=CC=C1)OC

Computational Chemistry Data

TPSA 18.46
LogP 4.1333
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 3

Safety Information

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GHS Pictogram :	GHS No : GHS05,GHS09
Signal Word : Danger	UN#: 3077
Class : 9	Packing Group : Ⅲ
Hazard Statements : H318-H410
Precautionary Statements : P273-P280-P391-P501

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Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2'-Bromo-2,6-dimethoxy-1,1'-biphenyl

CAS No. 755017-61-9

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