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CS-W001157 4
Total: USD 88.00

(3aR,6R,6aR)-6-(((tert-Butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one

  • CAS No. 75467-36-6

  • Cat. No. CS-0084802
  • Purity≥95%
  • MDL No.MFCD00216623

*For research and further manufacturing use only, not for direct human use.

(3aR,6R,6aR)-6-(((tert-Butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one|CS-0084802

Structure of 75467-36-6

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General Information

  • CAS No. 75467-36-6
  • Cat. No. CS-0084802
  • Purity ≥95%
  • MDL No. MFCD00216623
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₄H₂₆O₅Si
  • Molecular Weight 302.44
  • Synonym(s) 5-O-tert-Butyldimethylsilyl-2,3-O-isopropylidene-D-lyxono-1,4-lactone
  • SMILES O=C1O[C@H](CO[Si](C(C)(C)C)(C)C)[C@@]2([H])OC(C)(C)O[C@]21[H]

Synthesis

  • Route1

    References

    • Jones, Nigel A.; Jenkinson, Sarah F.; Soengas, Raquel; Fanefjord, Mette; Wormald, Mark R.; Dwek, Raymond A.; Kiran, Gullapalli P.; Devendar, Rao; Takata, Goro; Morimoto, Kenji; Izumori, Ken; Fleet, George W.J. Tetrahedron Asymmetry, 2007 , vol. 18, # 6 p. 774 - 786
  • Route2

    References

    • Alessandrini, Laura; Casati, Silvana; Ciuffreda, Pierangela; Ottria, Roberta; Santaniello, Enzo Journal of Carbohydrate Chemistry, 2008 , vol. 27, # 5 p. 332 - 344
  • Route3
    • b-D-Ribofuranose, 2,3-O-(1-methylethylidene)-|CS-0001514
      67814-68-0
    • ~%
    • (3aR,6R,6aR)-6-(((tert-Butyldimethylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one|CS-0084802
      75467-36-6

    References

    • Tetrahedron, , vol. 60, # 31 p. 6609 - 6617

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P330-P501

Quality Control

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Computational Chemistry Data

  • TPSA   53.99
  • LogP   2.4537
  • H_Acceptors   5
  • H_Donors   0
  • Rotatable_Bonds   3

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