Ethyl 5-amino-2-methylbenzoate

Name: Ethyl 5-amino-2-methylbenzoate
Brand: ChemScene
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CAS No. 7335-32-2
Cat. No. CS-0527934
Purity≥98%
MDL No.None

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Ethyl 5-amino-2-methylbenzoate|CS-0527934

Structure of 7335-32-2

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General Information

CAS No. 7335-32-2
Cat. No. CS-0527934
Purity ≥98%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₃NO₂
Molecular Weight 179.22
Synonym(s) ethyl-3-amino-6-methyl-benzoate
SMILES O=C(OCC)C1=CC(N)=CC=C1C

Description

Ethyl 5-amino-2-methylbenzoate features a conjugated aromatic core with complementary electron-donating amino and methyl groups, enabling efficient coupling in peptide and heterocyclic synthesis. The ethyl ester facilitates straightforward derivatization under standard conditions.

Application

Ethyl 5-amino-2-methylbenzoate serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient access to substituted benzimidazoles and other heterocyclic scaffolds. Its amino and ester functionalities offer orthogonal reactivity for sequential transformations, while the methyl group enhances metabolic stability. The compound exhibits excellent bench stability and is readily purified by standard chromatographic methods, facilitating integration into multi-step synthetic sequences.

Synthesis

Route1
- 124358-24-3
- ~99%
- In-stock
  
  7335-32-2
References
- Della Sala, Giorgio; Izzo, Irene; De Riccardis, Francesco; Sodano, Guido Tetrahedron Letters, 1998 , vol. 39, # 26 p. 4741 - 4744
Route2
- In-stock
  
  1975-52-6
- ~%
- In-stock
  
  7335-32-2
References
- Della Sala, Giorgio; Izzo, Irene; De Riccardis, Francesco; Sodano, Guido Tetrahedron Letters, 1998 , vol. 39, # 26 p. 4741 - 4744

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

Quality Control

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Computational Chemistry Data

TPSA 52.32
LogP 1.75392
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Ethyl 5-amino-2-methylbenzoate

CAS No. 7335-32-2

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