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CS-W001157 4
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(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene

  • CAS No. 72658-10-7

  • Cat. No. CS-0213764
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene|CS-0213764

Structure of 72658-10-7

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General Information

  • CAS No. 72658-10-7
  • Cat. No. CS-0213764
  • Purity ≥98%
  • MDL No. None
  • Storage Sealed in dry,2-8℃
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₂₂O₂Si
  • Molecular Weight 202.37
  • Synonym(s) tert-butyl trimethylsilyl methyl ketene acetal
  • SMILES C[Si](C)(C)O/C(OC(C)(C)C)=C/C

Synthesis

  • Route1

    References

    • NANYANG TECHNOLOGICAL UNIVERSITY; ZHOU, Steve, Jianrong; HUANG, Zhiyan Patent: WO2013/28132 A1, 2013 ; Location in patent: Paragraph 00181-00182 ;
  • Route2
    • null|null
      75-77-4
    • In-stock
      tert-butyl propionate|CS-0188223
      20487-40-5
    • ~71%
    • null|null
      57482-70-9
    • (1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene|CS-0213764
      72658-10-7

    References

    • Okabayashi, Tomohito; Iida, Akira; Takai, Kenta; Nawate, Yuuya; Misaki, Tomonori; Tanabe, Yoo Journal of Organic Chemistry, 2007 , vol. 72, # 21 p. 8142 - 8145
  • Route3
    • null|null
      75-77-4
    • In-stock
      tert-butyl propionate|CS-0188223
      20487-40-5
    • ~%
    • null|null
      72658-04-9
    • (1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene|CS-0213764
      72658-10-7

    References

    • Heathcock, Clayton H.; Buse, Charles T.; Kleschick, William A.; Pirrung, Michael C.; Sohn, John E.; Lampe, John Journal of Organic Chemistry, 1980 , vol. 45, # 6 p. 1066 - 1081

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Danger
UN#: 1993
Class : 3
Packing Group : Ⅲ
Hazard Statements : H225-H315-H319
Precautionary Statements : P210-P233-P240-P241-P242-P243-P264-P280-P302+P352-P362+P364-P370+P378-P501

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   3.5143
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   3

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