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CS-W001157 4
Total: USD 88.00

1-Bromo-4-(trimethylsilyl)benzene

  • CAS No. 6999-03-7

  • Cat. No. CS-D0587
  • Purity≥96%
  • MDL No.MFCD00094165

*For research and further manufacturing use only, not for direct human use.

1-Bromo-4-(trimethylsilyl)benzene|CS-D0587

Structure of 6999-03-7

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General Information

  • CAS No. 6999-03-7
  • Cat. No. CS-D0587
  • Purity ≥96%
  • MDL No. MFCD00094165
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₃BrSi
  • Molecular Weight None
  • Synonym(s) Silane, (4-bromophenyl)trimethyl-
  • SMILES C[Si](C)(C)C1=CC=C(Br)C=C1

Description

1-Bromo-4-(trimethylsilyl)benzene features a terminal bromide and a robust trimethylsilyl group positioned para to one another on the aromatic ring. This configuration enables seamless integration into cross-coupling reactions, where the silyl moiety serves as a stable, moisture-tolerant protecting group. The molecule exhibits excellent bench stability and compatibility with standard transition-metal catalysis protocols.

Synthesis

  • Route1
    • null|null
      75-77-4
    • In-stock
      1,4-Dibromobenzene|CS-0000003
      106-37-6
    • ~99%
    • In-stock
      1-Bromo-4-(trimethylsilyl)benzene|CS-D0587
      6999-03-7

    References

    • Itami, Kenichiro; Terakawa, Koji; Yoshida, Jun-ichi; Kajimoto, Okitsugu Journal of the American Chemical Society, 2003 , vol. 125, # 20 p. 6058 - 6059 Title/Abstract View citing articles Show Details Itami, Kenichiro; Terakawa, Koji; Yoshida, Jun-Ichi; Kajimoto, Okitsugu Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 11 p. 2071 - 2080
  • Route2
    • null|null
      75-77-4
    • null|null
      60-29-7
    • In-stock
      1,4-Dibromobenzene|CS-0000003
      106-37-6
    • ~92%
    • In-stock
      1-Bromo-4-(trimethylsilyl)benzene|CS-D0587
      6999-03-7

    References

    • LG DISPLAY CO., LTD. Patent: US2010/155714 A1, 2010 ;
  • Route3
    • null|null
      75-77-4
    • In-stock
      4-Bromoiodobenzene|CS-W008977
      589-87-7
    • ~97%
    • In-stock
      1-Bromo-4-(trimethylsilyl)benzene|CS-D0587
      6999-03-7

    References

    • Richter; De Wolf; Van Koten; Deelman Journal of Organic Chemistry, 2000 , vol. 65, # 13 p. 3885 - 3893

Safety Information

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GHS Pictogram : N/A
GHS No : N/A
Signal Word : N/A
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   2.9943
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   1

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