4-Chloro-N,N-dimethylaniline

Name: 4-Chloro-N,N-dimethylaniline
Brand: ChemScene
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CAS No. 698-69-1
Cat. No. CS-0151319
Purity≥96%
MDL No.MFCD07780200

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 698-69-1

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Description

4-Chloro-N,N-dimethylaniline is a bench-stable, electron-rich arylamine featuring a para-chloro substituent and dimethylamino group. This combination enhances its nucleophilicity and solubility in organic media, enabling efficient incorporation into coupling reactions and synthetic intermediates for pharmaceuticals and functional materials.

Application

4-Chloro-N,N-dimethylaniline serves as a versatile arylamine building block in pharmaceutical and agrochemical synthesis. Its electron-rich aromatic ring enables efficient Pd-catalyzed cross-coupling reactions, while the dimethylamino group provides strong resonance donation, enhancing reactivity in electrophilic substitutions. The chloro substituent offers a reliable handle for further functionalization via nucleophilic aromatic substitution or transition metal-mediated coupling. Bench-stable and readily purified by distillation or recrystallization, it functions effectively in multi-step synthetic sequences requiring high functional group tolerance and predictable regiochemistry.

General Information

CAS No. 698-69-1
Cat. No. CS-0151319
Purity ≥96%
MDL No. MFCD07780200
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₁₀ClN
Molecular Weight 155.62
Synonym(s) p-N,N-Dimethylaminochlorobenzene
SMILES CN(C)C1=CC=C(C=C1)Cl

Computational Chemistry Data

TPSA 3.24
LogP 2.406
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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4-Chloro-N,N-dimethylaniline

CAS No. 698-69-1

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