Tert-butyl (4-bromothiazol-2-yl)methylcarbamate

Name: Tert-butyl (4-bromothiazol-2-yl)methylcarbamate
Brand: ChemScene
Availability: InStock
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CAS No. 697299-87-9
Cat. No. CS-W001022
Purity≥98%
MDL No.MFCD13191707

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Tert-butyl (4-bromothiazol-2-yl)methylcarbamate|CS-W001022

Structure of 697299-87-9

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General Information

CAS No. 697299-87-9
Cat. No. CS-W001022
Purity ≥98%
MDL No. MFCD13191707
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₁₃BrN₂O₂S
Molecular Weight 293.18
Synonym(s) tert-butyl (4-bromothiazol-2-yl)methylcarbamate
SMILES CC(C)(C)OC(NCC1=NC(Br)=CS1)=O

Description

tert-Butyl ((4-bromothiazol-2-yl)methyl)carbamate delivers a stable, moisture-tolerant platform for installing brominated thiazole motifs in late-stage functionalization. This bench-stable carbamate anchors the 4-bromothiazol-2-ylmethyl group with high fidelity, enabling efficient coupling and diversification in medicinal chemistry and materials synthesis.

Application

tert-Butyl ((4-bromothiazol-2-yl)methyl)carbamate serves as a stable, bench-ready building block for the incorporation of bromothiazole motifs into complex molecules. The carbamate group enables straightforward deprotection under mild acidic conditions, while the pendant bromine supports diverse cross-coupling reactions, including Suzuki and Stille couplings. Its functional group tolerance and compatibility with standard synthetic workflows make it a reliable reagent for medicinal chemistry and process development.

Synthesis

Route1
- 697299-86-8
- In-stock
  
  24424-99-5
- ~74%
- In-stock
  
  697299-87-9
References
- Wallace, Eli; Topolov, George; Zhao, Qian; Lyssikatos, Joseph P. Patent: US2005/101617 A1, 2005 ; Location in patent: Page/Page column 10 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H320-H335
Precautionary Statements : P261-P280-P302+P352

Quality Control

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Computational Chemistry Data

TPSA 51.22
LogP 2.9303
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Thiazole compounds

Key Words

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Tert-butyl (4-bromothiazol-2-yl)methylcarbamate

CAS No. 697299-87-9

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