6,6'-Di-tert-butyl-2,2'-bipyridine

Name: 6,6'-Di-tert-butyl-2,2'-bipyridine
Brand: ChemScene
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CAS No. 6859-28-5
Cat. No. CS-0565003
Purity≥98%
MDL No.MFCD24449700

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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6,6'-Di-tert-butyl-2,2'-bipyridine|CS-0565003

Structure of 6859-28-5

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General Information

CAS No. 6859-28-5
Cat. No. CS-0565003
Purity ≥98%
MDL No. MFCD24449700
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₈H₂₄N₂
Molecular Weight 268.40
Synonym(s) None
SMILES N=1C(=CC=CC1C(C)(C)C)C=2N=C(C=CC2)C(C)(C)C

Description

6,6'-Di-tert-butyl-2,2'-bipyridine features two bulky tert-butyl groups flanking the bipyridine core, enhancing steric protection and improving solubility in organic media. This electron-rich ligand stabilizes low-valent metal complexes and facilitates redox-active coordination in catalytic systems.

Application

6,6'-Di-tert-butyl-2,2'-bipyridine serves as a sterically hindered bipyridine ligand that enables robust coordination to transition metals, particularly in catalytic systems requiring enhanced stability and reduced ligand dissociation. Its bulky tert-butyl groups confer excellent bench stability, facilitate easy purification, and improve solubility in nonpolar solvents, making it well-suited for applications in homogeneous catalysis and redox-active complexes.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

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Computational Chemistry Data

TPSA 25.78
LogP 4.7386
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Key Words

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6,6'-Di-tert-butyl-2,2'-bipyridine

CAS No. 6859-28-5

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