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CS-W001157 4
Total: USD 88.00

Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate

  • CAS No. 680-15-9

  • Cat. No. CS-0107267
  • Purity≥97%
  • MDL No.MFCD00144316

*For research and further manufacturing use only, not for direct human use.

Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate|CS-0107267

Structure of 680-15-9

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General Information

  • CAS No. 680-15-9
  • Cat. No. CS-0107267
  • Purity ≥97%
  • MDL No. MFCD00144316
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃H₃F₃O₄S
  • Molecular Weight 192.11
  • Synonym(s) None
  • SMILES O=C(OC)C(F)(F)S(=O)(F)=O

Description

Useful reagent for the trifluoromethylation of alkyl halides.Broadly applicable reagent for perfluoroalkylations for aryl iodides and bromides

Synthesis

  • Route1
    • null|null
      697-18-7
    • null|null
      124-41-4
    • ~49%
    • In-stock
      Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate|CS-0107267
      680-15-9

    References

    • England,D.C. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 6181 - 6188 Full Text View citing articles Show Details Gmelin Handbook: F: PerFHalOrg.2, 1.3.2, page 99 - 119
  • Route2
    • null|null
      62949-75-1
    • ~%
    • null|null
      378-75-6
    • In-stock
      Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate|CS-0107267
      680-15-9

    References

    • Journal of the American Chemical Society, , vol. 99, p. 1214 - 1217
  • Route3
    • null|null
      67-56-1
    • null|null
      62949-75-1
    • ~%
    • In-stock
      Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate|CS-0107267
      680-15-9

    References

    • Journal of the American Chemical Society, , vol. 99, p. 1214 - 1217

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS05
Signal Word : Danger
UN#: 2920
Class : 8(3)
Packing Group : Ⅱ
Hazard Statements : H226-H314
Precautionary Statements : P210-P233-P240-P241-P242-P243-P260-P264-P280-P301+P330+P331-P304+P340-P363-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   60.44
  • LogP   0.0515
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   2

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