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CS-W001157 4
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Methyl 3-(hydroxymethyl)benzoate

  • CAS No. 67853-03-6

  • Cat. No. CS-0096392
  • Purity≥98%
  • MDL No.None
  • HazMat Fee +

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    Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

    If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

    There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Methyl 3-(hydroxymethyl)benzoate|CS-0096392

Structure of 67853-03-6

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Description

Methyl 3-(hydroxymethyl)benzoate features a benzene ring bearing both a methyl ester and a pendant hydroxymethyl group, enabling versatile functionalization. This ortho-substituted aromatic ester offers enhanced solubility in polar solvents and stability under standard bench conditions. The hydroxymethyl moiety facilitates derivatization for synthesis of bioactive compounds, polymer linkers, or fluorescent probes.

Application

Methyl 3-(hydroxymethyl)benzoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to functionalized benzene derivatives. The pendant hydroxymethyl group facilitates oxidation to the carboxylic acid, reduction to the primary alcohol, or ether formation, while the ester functionality supports cross-coupling and nucleophilic transformations. Its bench-stable nature and compatibility with standard purification protocols make it well-suited for iterative synthesis workflows in medicinal chemistry and materials development.

General Information

  • CAS No. 67853-03-6
  • Cat. No. CS-0096392
  • Purity ≥98%
  • MDL No. None
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₀O₃
  • Molecular Weight 166.17
  • Synonym(s) 3-hydroxymethylbenzoic acid methyl ester
  • SMILES O=C(OC)C1=CC=CC(CO)=C1

Computational Chemistry Data

  • TPSA   46.53
  • LogP   0.9655
  • H_Acceptors   3
  • H_Donors   1
  • Rotatable_Bonds   2

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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