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CS-W001157 4
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[1,1'-Biphenyl]-3,4',5-tricarboxylic acid

  • CAS No. 677010-20-7

  • Cat. No. CS-0110044
  • Purity≥97%
  • MDL No.MFCD16621432

*For research and further manufacturing use only, not for direct human use.

[1,1'-Biphenyl]-3,4',5-tricarboxylic acid|CS-0110044

Structure of 677010-20-7

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General Information

  • CAS No. 677010-20-7
  • Cat. No. CS-0110044
  • Purity ≥97%
  • MDL No. MFCD16621432
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₅H₁₀O₆
  • Molecular Weight 286.24
  • Synonym(s) 3,5,4'-Biphenyltricarboxylic acid
  • SMILES O=C(O)C=1C=CC(=CC1)C2=CC(=CC(=C2)C(=O)O)C(=O)O

Description

1,1'-Biphenyl]-3,4',5-tricarboxylic acid features three carboxylate groups positioned at the 3, 4', and 5-positions of the biphenyl core, enabling strong coordination in metal-organic frameworks. The extended aromatic system provides rigidity and planarity, enhancing structural stability. This molecule integrates readily into conjugated systems and serves as a robust building block for functional materials.

Application

[1,1'-Biphenyl]-3,4',5-tricarboxylic acid serves as a versatile building block for constructing complex heterocyclic systems and functionalized aromatic scaffolds. Its three carboxylic acid groups enable efficient derivatization via esterification, amide coupling, or metal coordination, facilitating applications in ligand design and polymer synthesis. The biphenyl core provides structural rigidity and enhanced π-conjugation, while the ortho-substitution pattern ensures predictable reactivity and stability under standard synthetic conditions.

Synthesis

  • Route1

    References

    • Park, Tae-Hong; Cychosz, Katie A.; Wong-Foy, Antek G.; Dailly, Anne; Matzger, Adam J. Chemical Communications, 2011 , vol. 47, # 5 p. 1452 - 1454
  • Route2

    References

    • Sukul, Pradip K.; Malik, Sudip RSC Advances, 2013 , vol. 3, # 6 p. 1902 - 1915
  • Route3

    References

    • Sukul, Pradip K.; Malik, Sudip RSC Advances, 2013 , vol. 3, # 6 p. 1902 - 1915

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS09
Signal Word : Warning
UN#: 3077
Class : 9
Packing Group : Ⅲ
Hazard Statements : H315-H319-H335-H400
Precautionary Statements : P273-P302+P352

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Computational Chemistry Data

  • TPSA   111.9
  • LogP   2.4482
  • H_Acceptors   3
  • H_Donors   3
  • Rotatable_Bonds   4

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