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CS-W001157 4
Total: USD 88.00

1-Cyclohexenyloxytrimethylsilane

  • CAS No. 6651-36-1

  • Cat. No. CS-0204290
  • Purity≥95%
  • MDL No.MFCD00001541

*For research and further manufacturing use only, not for direct human use.

1-Cyclohexenyloxytrimethylsilane|CS-0204290

Structure of 6651-36-1

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General Information

  • CAS No. 6651-36-1
  • Cat. No. CS-0204290
  • Purity ≥95%
  • MDL No. MFCD00001541
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₈OSi
  • Molecular Weight 170.32
  • Synonym(s) Silane, (1-cyclohexen-1-yloxy)trimethyl-
  • SMILES O(C1=CCCCC1)[Si](C)(C)C

Description

1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of 1,9- octalone. It is intermediate to many complex compounds including natural products.

Synthesis

  • Route1
    • In-stock
      Trimethylsilyl trifluoromethylsulfonate|CS-B0886
      27607-77-8
    • null|null
      108-94-1
    • ~86%
    • In-stock
      1-Cyclohexenyloxytrimethylsilane|CS-0204290
      6651-36-1

    References

    • Schroth, Werner; Jahn, Ullrich; Stroehl, Dieter Chemische Berichte, 1994 , vol. 127, # 10 p. 2013 - 2022
  • Route2
    • null|null
      63408-33-3
    • ~78%
    • In-stock
      1-Cyclohexenyloxytrimethylsilane|CS-0204290
      6651-36-1

    References

    • Hurdlik, Paul F.; Hudrlik, Anne M.; Kulkarni Ashok K. Journal of the American Chemical Society, 1985 , vol. 107, # 14 p. 4260 - 4264
  • Route3
    • In-stock
      [(1-Methoxy-1-propenyl)oxy]trimethylsilane|CS-0207587
      34880-70-1
    • null|null
      108-94-1
    • ~68%
    • In-stock
      1-Cyclohexenyloxytrimethylsilane|CS-0204290
      6651-36-1

    References

    • Kita, Yasuyuki; Yasuda, Hitoshi; Haruta, Jun-ichi; Segawa, Jun; Tamura, Yasumitsu Synthesis, 1982 , # 12 p. 1089 - 1091

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02
Signal Word : Warning
UN#: 1993
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226-H412
Precautionary Statements : P210-P233-P240-P241-P242-P243-P273-P280-P370+P378-P501

Quality Control

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Computational Chemistry Data

  • TPSA   9.23
  • LogP   3.2958
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   2

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