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CS-W001157 4
Total: USD 88.00

Benzeneselenol

  • CAS No. 645-96-5

  • Cat. No. CS-0197351
  • Purity≥98%
  • MDL No.MFCD00000001

*For research and further manufacturing use only, not for direct human use.

Benzeneselenol|CS-0197351

Structure of 645-96-5

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General Information

  • CAS No. 645-96-5
  • Cat. No. CS-0197351
  • Purity ≥98%
  • MDL No. MFCD00000001
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₆H₆Se
  • Molecular Weight 157.07
  • Synonym(s) Phenylselenol
  • SMILES C1=CC=C(C=C1)[SeH]

Description

Benzeneselenol is an aryl selenol. Diphenyl diselenide-promoted radical addition of benzeneselenol to inactivated acetylenes upon irradiation through Pyrex with a tungsten lamp has been reported. Catalysis of stannane-mediated radical chain reactions by benzeneselenol, generated in situ by reduction of diphenyl diselenide with tributyltin hydride, has been reported.Benzeneselenol may be used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes. It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes.

Synthesis

  • Route1
    • null|null
      1666-13-3
    • ~98%
    • In-stock
      Benzeneselenol|CS-0197351
      645-96-5

    References

    • Santi, Claudio; Santoro, Stefano; Testaferri, Lorenzo; Marcello Tiecco Synlett, 2008 , # 10 p. 1471 - 1474
  • Route2
    • Trimethyl(Phenylselanyl)silane|CS-0768500
      33861-17-5
    • ~94%
    • null|null
      75-77-4
    • In-stock
      Benzeneselenol|CS-0197351
      645-96-5

    References

    • Journal of Organic Chemistry, , vol. 46, # 7 p. 1283 - 1292
  • Route3
    • null|null
      7782-49-2
    • null|null
      108-86-1
    • ~58%
    • In-stock
      Benzeneselenol|CS-0197351
      645-96-5

    References

    • Sun, Jiangtao; Yang, Minghua; Yuan, Fang; Jia, Xuefeng; Yang, Xia; Pan, Yi; Zhu, Chengjian Advanced Synthesis and Catalysis, 2009 , vol. 351, # 6 p. 920 - 930

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS06,GHS08,GHS09
Signal Word : Danger
UN#: 2810
Class : 6.1
Packing Group : Ⅲ
Hazard Statements : H227-H301+H331-H373-H410
Precautionary Statements : P210-P260-P261-P264-P270-P271-P273-P280-P304+P340-P330-P370+P378-P391-P403-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   0.2127
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   0

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