N6-Benzoyl-5′-O-(4,4′-dimethoxytrityl)-2′-deoxyadenosine

Name: N6-Benzoyl-5′-O-(4,4′-dimethoxytrityl)-2′-deoxyadenosine
Brand: ChemScene
Availability: InStock
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CAS No. 64325-78-6
Cat. No. CS-W013793
Purity≥97%
MDL No.MFCD00010058

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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N6-Benzoyl-5′-O-(4,4′-dimethoxytrityl)-2′-deoxyadenosine|CS-W013793

Structure of 64325-78-6

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General Information

CAS No. 64325-78-6
Cat. No. CS-W013793
Purity ≥97%
MDL No. MFCD00010058
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₈H₃₅N₅O₆
Molecular Weight 657.71
Synonym(s) None
SMILES O[C@H]1C[C@H](N2C(N=CN=C3NC(C4=CC=CC=C4)=O)=C3N=C2)O[C@@H]1COC(C5=CC=C(OC)C=C5)(C6=CC=C(OC)C=C6)C7=CC=CC=C7

Description

N6-Benzoyl-5′-O-(4,4′-dimethoxytrityl)-2′-deoxyadenosine features a protected adenine base and a labile trityl group at the 5′-position, enabling controlled chain elongation in oligonucleotide synthesis. The benzoyl moiety stabilizes the N6 position against depurination, while the dimethoxytrityl group facilitates selective 5′-end activation under standard coupling conditions. This derivative ensures high fidelity during automated solid-phase synthesis of DNA sequences.

Synthesis

Route1
- In-stock
  
  40615-36-9
- In-stock
  
  4546-72-9
- ~81%
- In-stock
  
  64325-78-6
References
- Tetrahedron Letters, , vol. 33, # 48 p. 7319 - 7323
Route2
- 118352-75-3
- ~84%
- In-stock
  
  64325-78-6
References
- Tetrahedron Letters, , vol. 40, # 35 p. 6477 - 6480
Route3
- In-stock
  
  958-09-8
- ~%
- In-stock
  
  64325-78-6
References
- Helvetica Chimica Acta, , vol. 65, # 8 p. 2372 - 2393

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 129.85
LogP 5.7529
H_Acceptors 10
H_Donors 2
Rotatable_Bonds 11

Other Classifications

Life Science Nucleosides & Nucleotides Ribonucleotide

Chemical Biology Pharmaceutical Development and Drug Discovery Research Nucleic Acid Chemistry Protected Nucleosides

Biochemistry Biochemicals and Reagents Nucleosides, Nucleotides, Oligonucleotides Nucleoside Analogs

Biochemistry Biochemicals and Reagents Nucleosides, Nucleotides, Oligonucleotides Nucleosides

Chemical Biology Pharmaceutical Development and Drug Discovery Research Reagents Nucleic Acid Chemistry Protected Nucleosides

Key Words

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N6-Benzoyl-5′-O-(4,4′-dimethoxytrityl)-2′-deoxyadenosine

CAS No. 64325-78-6

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