Lot numbers can be found on the outside label of a product:
4-Chloro-N-methoxy-N-methylbutanamide
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CAS No. 64214-66-0
- Cat. No. CS-0046358
- Purity≥97%
- MDL No.MFCD18327515
*For research and further manufacturing use only, not for direct human use.
Structure of 64214-66-0
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General Information
- CAS No. 64214-66-0
- Cat. No. CS-0046358
- Purity ≥97%
- MDL No. MFCD18327515
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₆H₁₂ClNO₂
- Molecular Weight 165.62
- Synonym(s) Butanamide, 4-chloro-N-methoxy-N-methyl-
- SMILES O=C(N(OC)C)CCCCl
Description
4-Chloro-N-methoxy-N-methylbutanamide is a versatile acylating agent featuring a chlorinated aliphatic chain and dual N-alkoxy substituents. This configuration enhances reactivity while maintaining stability under standard bench conditions, enabling efficient amide bond formation in synthetic workflows.
Application
4-Chloro-N-methoxy-N-methylbutanamide serves as a versatile acylating agent in synthetic organic chemistry, enabling efficient amide bond formation under mild conditions. Its chloro-substituted aliphatic backbone provides enhanced reactivity while maintaining bench stability and ease of handling. The N-methoxy-N-methyl group facilitates clean displacement reactions, making it well-suited for peptide synthesis and the construction of complex heterocyclic scaffolds.
Synthesis
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References
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GLAXO GROUP LIMITED Patent: WO2005/37197 A2, 2005 ; Location in patent: Page/Page column 104 ; WO 2005/037197 A2
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Route2
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3153-36-4 -
In-stock
6638-79-5 - ~98%
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In-stock
64214-66-0
References
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Shimizu, Takeshi; Osako, Katsuhisa; Nakata, Tadashi Tetrahedron Letters, 1997 , vol. 38, # 15 p. 2685 - 2688
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Route3
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In-stock
4635-59-0 -
1117-97-1
- ~78%
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In-stock
64214-66-0
References
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Murphy, John A.; Commeureuc, Aurelien G. J.; Snaddon, Thomas N.; McGuire, Thomas M.; Khan, Tanweer A.; Hisler, Kevin; Dewis, Mark L.; Carling, Robert Organic Letters, 2005 , vol. 7, # 7 p. 1427 - 1429
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Safety Information
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GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 29.54
- LogP 1.0252
- H_Acceptors 2
- H_Donors 0
- Rotatable_Bonds 4
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Key Words
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