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CS-W001157 4
Total: USD 88.00

4-Methoxystyrene stabilized with TBC

  • CAS No. 637-69-4

  • Cat. No. CS-W013377
  • Purity97% (stabilized with TBC)
  • MDL No.MFCD00008619

*For research and further manufacturing use only, not for direct human use.

4-Methoxystyrene stabilized with TBC|CS-W013377

Structure of 637-69-4

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General Information

  • CAS No. 637-69-4
  • Cat. No. CS-W013377
  • Purity 97% (stabilized with TBC)
  • MDL No. MFCD00008619
  • Storage -20°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₀O
  • Molecular Weight 134.18
  • Synonym(s) 4-Vinylanisole (stabilized with TBC)
  • SMILES O(C1=CC=C(C=C)C=C1)C

Description

Fmoc-PEG3-CH2CO2-NHS is a PEG linker containing an Fmoc group and an NHS ester group. The hydrophilic PEG spacer increases solubility in aqueous media. The NHS ester can be used to label the primary amines (-NH2) of proteins, amine-modified oligonucleotides, and other amine-containing molecules. The Fmoc group can be deprotected under basic condition to obtain the free amine which can be used for further conjugations.

Application

1-Methoxy-4-vinylbenzene (stabilized with TBC) serves as a versatile vinyl monomer for polymer synthesis and cross-coupling reactions. Its methoxy group provides electron-donating activation, enhancing reactivity in palladium-catalyzed transformations. The stabilized form ensures bench stability and safe handling, enabling reliable incorporation into functional polymers, advanced materials, and heterocyclic scaffold construction.

Synthesis

  • Route1
    • null|null
      623-12-1
    • null|null
      7486-35-3
    • ~89%
    • In-stock
      4-Methoxystyrene stabilized with TBC|CS-W013377
      637-69-4

    References

    • Su, Weiping; Urgaonkar, Sameer; Verkade, John G. Organic Letters, 2004 , vol. 6, # 9 p. 1421 - 1424
  • Route2
    • null|null
      1112-55-6
    • In-stock
      4-Iodoanisole|CS-W003965
      696-62-8
    • ~94%
    • In-stock
      4-Methoxystyrene stabilized with TBC|CS-W013377
      637-69-4

    References

    • Grirrane, Abdessamad; Garcia, Hermenegildo; Corma, Avelino Journal of Catalysis, 2013 , vol. 302, p. 49 - 57
  • Route3
    • In-stock
      4-Iodoanisole|CS-W003965
      696-62-8
    • null|null
      754-05-2
    • ~82%
    • In-stock
      4-Methoxystyrene stabilized with TBC|CS-W013377
      637-69-4
    • null|null
      76711-42-7

    References

    • Journal of Catalysis, , vol. 302, p. 49 - 57

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   9.23
  • LogP   2.3382
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   2

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