1,10-Phenanthroline-5-carboxylic acid

Name: 1,10-Phenanthroline-5-carboxylic acid
Brand: ChemScene
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CAS No. 630067-06-0
Cat. No. CS-W004571
Molecule weight224.22
Purity≥98%
MDL No.MFCD06255104

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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1,10-Phenanthroline-5-carboxylic acid|CS-W004571

Structure of 630067-06-0

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General Information

CAS No. 630067-06-0
Cat. No. CS-W004571
Purity ≥98%
MDL No. MFCD06255104
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₃H₈N₂O₂
Molecular Weight 224.22
Synonym(s) None
SMILES O=C(O)C1=CC2=CC=CN=C2C=3N=CC=CC31

Description

1,10-Phenanthroline-5-carboxylic acid features a rigid aromatic scaffold with a carboxylate group at the 5-position, enabling strong metal chelation and enhanced solubility. The para-substituted carboxylic acid integrates seamlessly into coordination networks, offering tunable ligand properties for catalytic and supramolecular applications.

Application

1,10-Phenanthroline-5-carboxylic acid serves as a versatile chelating ligand and building block in transition metal catalysis and coordination chemistry. Its carboxylic acid functionality enables direct conjugation to polymers or solid supports, while the phenanthroline core provides strong metal binding affinity, particularly for copper and iron complexes. The molecule exhibits good bench stability and facilitates purification via standard chromatographic methods, making it suitable for use in homogeneous catalysis, electrochemical studies, and the synthesis of functionalized heterocyclic scaffolds.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 63.08
LogP 2.4812
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Phenanthroline Ligands

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Phenanthroline Ligands

Key Words

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1,10-Phenanthroline-5-carboxylic acid

CAS No. 630067-06-0

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