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CS-W001157 4
Total: USD 88.00

Ethynyltriphenylsilane

  • CAS No. 6229-00-1

  • Cat. No. CS-W012236
  • Purity≥98%
  • MDL No.MFCD00075453

*For research and further manufacturing use only, not for direct human use.

Ethynyltriphenylsilane|CS-W012236

Structure of 6229-00-1

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General Information

  • CAS No. 6229-00-1
  • Cat. No. CS-W012236
  • Purity ≥98%
  • MDL No. MFCD00075453
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₀H₁₆Si
  • Molecular Weight 284.43
  • Synonym(s) ethynyl(triphenyl)silane
  • SMILES C#C[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Description

(Triphenylsilyl)acetylene is a terminal alkyne. Rhodium-catalyzed asymmetric addition of (triphenylsilyl)acetylene to diphenylphosphinylallene is reported.(Triphenylsilyl)acetylene may be used in the synthesis of:selenothioic acid S-alkyl estersmethyl 2-(di{ 3, 5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoate2-(di{3,5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoic acid

Synthesis

  • Route1
    • null|null
      76-86-8
    • null|null
      70277-75-7
    • ~69%
    • In-stock
      Ethynyltriphenylsilane|CS-W012236
      6229-00-1

    References

    • Ochida, Atsuko; Ito, Hideto; Sawamura, Masaya Journal of the American Chemical Society, 2006 , vol. 128, # 51 p. 16486 - 16487
  • Route2
    • null|null
      76-86-8
    • null|null
      74-86-2
    • ~76%
    • In-stock
      Ethynyltriphenylsilane|CS-W012236
      6229-00-1

    References

    • Denmark, Scott E.; Habermas, Karl L.; Hite, Gary A.; Jones, Todd K. Tetrahedron, 1986 , vol. 42, # 11 p. 2821 - 2829
  • Route3
    • null|null
      76-86-8
    • null|null
      4301-14-8
    • ~67%
    • In-stock
      Ethynyltriphenylsilane|CS-W012236
      6229-00-1

    References

    • Naka, Akinobu; Ishikawa, Mitsuo Journal of Organometallic Chemistry, 2000 , vol. 611, # 1-2 p. 248 - 255

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   2.3292
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   3

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