(E)-3-Methoxyacrylic acid

Name: (E)-3-Methoxyacrylic acid
Brand: ChemScene
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CAS No. 6214-29-5
Cat. No. CS-0201343
Molecule weight102.09
Purity≥97%
MDL No.None

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Type	HazMat Fee
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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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General Information

CAS No. 6214-29-5
Cat. No. CS-0201343
Purity ≥97%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄H₆O₃
Molecular Weight 102.09
Synonym(s) 3t-Methoxy-acrylsaeure
SMILES O=C(O)/C=C/OC

Description

(E)-3-Methoxyacrylic acid is a sterically constrained, electron-deficient enoate featuring a methoxy group at the β-position. This configuration enables direct participation in conjugate additions and Diels-Alder reactions under mild conditions. The compound exhibits enhanced stability compared to its α,β-unsaturated analogs, facilitating handling in synthetic workflows involving nucleophilic attack or polymerization initiation.

Application

(E)-3-Methoxyacrylic acid serves as a versatile building block for conjugated systems, enabling efficient access to α,β-unsaturated esters and amides via standard coupling reactions. Its stabilized enolate character facilitates Michael additions and Diels-Alder cycloadditions, while the methoxy group enhances solubility and offers a handle for further derivatization. Bench-stable and readily purified by recrystallization, it functions reliably in synthetic sequences requiring controlled reactivity and functional group compatibility.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 46.53
LogP 0.2311
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Carboxylic Acid

Building Blocks Functional Group Olefins

Building Blocks Skeleton Fatty chain compounds

Key Words

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(E)-3-Methoxyacrylic acid

CAS No. 6214-29-5

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