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CS-W001157 4
Total: USD 88.00

(E)-3-Bromoacrylic acid

  • CAS No. 6213-89-4

  • Cat. No. CS-0063842
  • Purity≥97%
  • MDL No.MFCD00218760
  • HazMat Fee +

    HazMat Fee

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

    The shipment is processed through FedEx Ground under the Limited Quantity option.

    Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

    If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

    There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

(E)-3-Bromoacrylic acid|CS-0063842

Structure of 6213-89-4

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Description

(E)-3-Bromoacrylic acid is a bench-stable, electron-deficient alkene featuring a conjugated bromo-acid functionality. This configuration enables direct incorporation into Michael addition reactions and cross-coupling protocols. The para-orientation of the halogen enhances reactivity in palladium-catalyzed transformations while maintaining compatibility with common protecting groups.

Application

(E)-3-Bromoacrylic acid serves as a versatile building block for the synthesis of substituted acrylates and conjugated systems. Its well-defined stereochemistry enables reliable incorporation into Michael acceptors, heterocyclic scaffolds, and polymerizable monomers. The bromine substituent offers high functional group tolerance and facilitates subsequent cross-coupling reactions, including Suzuki-Miyaura and Stille couplings. Bench-stable and amenable to standard purification techniques, it functions effectively in both academic and industrial synthetic workflows.

General Information

  • CAS No. 6213-89-4
  • Cat. No. CS-0063842
  • Purity ≥97%
  • MDL No. MFCD00218760
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃H₃BrO₂
  • Molecular Weight 150.96
  • Synonym(s) trans-beta-Bromoacrylic acid
  • SMILES O=C(O)/C=C/Br

Computational Chemistry Data

  • TPSA   37.3
  • LogP   0.9796
  • H_Acceptors   1
  • H_Donors   1
  • Rotatable_Bonds   1

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 3261
Class : 8
Packing Group :
Hazard Statements : H314-H318
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

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