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CS-W001157 4
Total: USD 88.00

Dimethyl itaconate

  • CAS No. 617-52-7

  • Cat. No. CS-W022632
  • Purity≥96%
  • MDL No.MFCD00008446

*For research and further manufacturing use only, not for direct human use.

Dimethyl itaconate|CS-W022632

Structure of 617-52-7

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General Information

  • CAS No. 617-52-7
  • Cat. No. CS-W022632
  • Purity ≥96%
  • MDL No. MFCD00008446
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₁₀O₄
  • Molecular Weight 158.15
  • Synonym(s) None
  • SMILES C(C(C(OC)=O)=C)C(OC)=O

Description

Dimethyl itaconate undergoes enantioselective Rh(I)-catalyzed hydrogenation which can be enhanced by appropriate choice of substituents on aromatic ring of (1,2-diarylphosphinoxy)cyclohexane.Dimethyl itaconate may be used in functionalization of isotactic poly(propylene). It was used in crosslinking of polyesters: poly(isosorbide itaconate)and poly(isosorbide itaconate-co-succinate).

Synthesis

  • Route1

    References

    • Journal of Molecular Catalysis A: Chemical, , vol. 368-369, p. 24 - 30
  • Route2

    References

    • Synthetic Communications, , vol. 38, # 22 p. 3937 - 3946
  • Route3

    References

    • Journal of the American Chemical Society, , vol. 70, p. 3574

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS08
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H334-H401
Precautionary Statements : P261-P264-P273-P280-P285-P302+P352-P362-P501

Quality Control

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Computational Chemistry Data

  • TPSA   52.6
  • LogP   0.2787
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   3

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