2-Chloro-4-methylaniline

Name: 2-Chloro-4-methylaniline
Brand: ChemScene
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CAS No. 615-65-6
Cat. No. CS-W018296
Purity≥97%
MDL No.MFCD00007666

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 615-65-6
Cat. No. CS-W018296
Purity ≥97%
MDL No. MFCD00007666
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈ClN
Molecular Weight 141.60
Synonym(s) 4-Amino-3-chlorotoluene; 2-Chloro-4-methylaniline
SMILES NC1=CC=C(C)C=C1Cl

Description

2-Chloro-4-methylaniline features a chlorinated aromatic ring paired with an electron-donating methyl group, enabling selective coupling reactions in pharmaceutical intermediates. This bench-stable derivative integrates efficiently into heterocyclic scaffolds under standard conditions.

Application

2-Chloro-4-methylaniline serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling direct incorporation of both chloro and methyl substituents on an aniline scaffold. Its reactivity facilitates electrophilic substitution, palladium-catalyzed coupling reactions, and amide formation under standard conditions. The compound exhibits good bench stability and is readily purified by recrystallization or column chromatography, making it suitable for scalable synthesis workflows.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS05
Signal Word : Danger	UN#: 3429
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H302+H312+H332-H315-H318-H412
Precautionary Statements : P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P363-P405-P501

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Computational Chemistry Data

TPSA 26.02
LogP 2.23062
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Chloro-4-methylaniline

CAS No. 615-65-6

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