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CS-W001157 4
Total: USD 88.00

1,2,4-Tribromobenzene

  • CAS No. 615-54-3

  • Cat. No. CS-0157156
  • Purity≥98%
  • MDL No.MFCD00000062

*For research and further manufacturing use only, not for direct human use.

1,2,4-Tribromobenzene|CS-0157156

Structure of 615-54-3

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General Information

  • CAS No. 615-54-3
  • Cat. No. CS-0157156
  • Purity ≥98%
  • MDL No. MFCD00000062
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₆H₃Br₃
  • Molecular Weight 314.80
  • Synonym(s) Benzene, 1,2,4-tribromo-
  • SMILES C1=CC(=C(C=C1Br)Br)Br

Description

1,2,4-tribromobenzene on photochemical dehalogenation in open-air solutions of acetonitrile yields 1,4-dibromobenzene, 1,3-dibromobenzene and 1,2-dibromobenzene.1,2,4-tribromobenzene was used in the synthesis of hyperbranched poly(p-phenylene ethynylenes). It was used as cross-linking reagent during Pd-catalyzed cross-coupling of 2,5-diiodo-4-[(2-ethylhexyl)oxy]methoxybenzene and 1,4-diethynyl-2,5-bis-(octyloxy)benzene.

Synthesis

  • Route1

    References

    • Prakash, G. K. Surya; Mathew, Thomas; Hoole, Dushyanthi; Esteves, Pierre M.; Wang, Qi; Rasul, Golam; Olah, George A. Journal of the American Chemical Society, 2004 , vol. 126, # 48 p. 15770 - 15776
  • Route2
    • In-stock
      1,2,4,5-Tetrabromobenzene|CS-0110360
      636-28-2
    • null|null
      92273-73-9
    • ~0%
    • In-stock
      1,2,4-Tribromobenzene|CS-0157156
      615-54-3
    • null|null
      52007-95-1

    References

    • Larrosa, Igor; Somoza, Clara; Banquy, Alexandre; Goldup, Stephen M. Organic Letters, 2011 , vol. 13, # 1 p. 146 - 149
  • Route3

    References

    • Journal of the Chemical Society, , p. 573,576

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS09
Signal Word : Warning
UN#: 3077
Class : 9
Packing Group : Ⅲ
Hazard Statements : H315-H319-H335-H410
Precautionary Statements : P273-P302+P352

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.9741
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   0

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