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CS-W001157 4
Total: USD 88.00

N-Nitrosomorpholine

  • CAS No. 59-89-2

  • Cat. No. CS-0128913
  • Purity≥97%
  • MDL No.MFCD00039710

*For research and further manufacturing use only, not for direct human use.

N-Nitrosomorpholine|CS-0128913

Structure of 59-89-2

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General Information

  • CAS No. 59-89-2
  • Cat. No. CS-0128913
  • Purity ≥97%
  • MDL No. MFCD00039710
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄H₈N₂O₂
  • Molecular Weight 116.12
  • Synonym(s) None
  • SMILES O=NN1CCOCC1

Description

Ethyl acetoacetate can be used as a reactant to synthesize: 7-hydroxycoumarin derivatives via Pechmann condensation reaction with 1,3-dihydroxybenzene in the presence of acid catalysts.2,6-disubstituted piperidine alkaloid, ()-pinidinone via stereoselective -aminoallylation followed by Grubbs olefin cross-metathesis reaction. Michael addition products via Michael addition reaction with chalcones and azachalcones in the presence of a base catalyst., -unsaturated carbonyl compounds via Knoevenagel condensation reaction with glyceraldehyde acetonide in the presence of a base catalyst. It can be also utilized as a reactant in the transesterification and asymmetric hydrogenation reactions to produce valuable products.

Synthesis

  • Route1
    • null|null
      110-91-8
    • ~97%
    • In-stock
      N-Nitrosomorpholine|CS-0128913
      59-89-2

    References

    • Zolfigol; Zebarjadian; Chehardoli; Keypour; Salehzadeh; Shamsipur Journal of Organic Chemistry, 2001 , vol. 66, # 10 p. 3619 - 3620
  • Route2
    • null|null
      110-91-8
    • null|null
      128767-05-5
    • ~22%
    • 1H-Benzo[d][1,2,3]triazole Bortezomib Impurity|CS-0229225
      95-14-7
    • In-stock
      N-Nitrosomorpholine|CS-0128913
      59-89-2

    References

    • Organic letters, , vol. 4, # 19 p. 3227 - 3229
  • Route3
    • null|null
      110-91-8
    • ~13%
    • In-stock
      N-Nitrosomorpholine|CS-0128913
      59-89-2
    • null|null
      4164-32-3

    References

    • Russian Chemical Bulletin, , vol. 58, # 10 p. 2043 - 2046

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS06,GHS08
Signal Word : Danger
UN#: 2811
Class : 6.1
Packing Group : Ⅲ
Hazard Statements : H301-H351
Precautionary Statements : P264-P270-P330-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   41.9
  • LogP   0
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   1

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