7-Fluoro-3,4-dihydro-2H-benzo[b][1,4]oxazine

Name: 7-Fluoro-3,4-dihydro-2H-benzo[b][1,4]oxazine
Brand: ChemScene
Availability: InStock
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CAS No. 56346-41-9
Cat. No. CS-0130060
Molecule weightNone
Purity≥96%
MDL No.MFCD11848177

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Type	HazMat Fee
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7-Fluoro-3,4-dihydro-2H-benzo[b][1,4]oxazine|CS-0130060

Structure of 56346-41-9

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General Information

CAS No. 56346-41-9
Cat. No. CS-0130060
Purity ≥96%
MDL No. MFCD11848177
Storage RT, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈FNO
Molecular Weight None
Synonym(s) 7-fluoro-3,4-dihydro-2H-1,4-benzoxazine
SMILES FC1=CC=C2NCCOC2=C1

Description

7-Fluoro-3,4-dihydro-2H-benzo[b][1,4]oxazine is a fluorinated heterocyclic scaffold featuring a fused benzene and oxazine ring system. This electron-deficient core enables selective incorporation into bioactive molecules, particularly in medicinal chemistry applications where enhanced metabolic stability and membrane permeability are required. The para-fluorine substitution modulates electronic properties without significant steric perturbation, supporting efficient derivatization under standard coupling conditions.

Application

7-Fluoro-3,4-dihydro-2H-benzo[b][1,4]oxazine serves as a versatile heterocyclic building block in medicinal chemistry, enabling the construction of bioactive scaffolds through standard functionalization at the dihydrooxazine ring. Its fluorinated aromatic system enhances metabolic stability and modulates electronic properties, while the saturated oxazine core offers site-specific reactivity for C–H functionalization, coupling reactions, and derivatization. Bench-stable and compatible with common purification methods, it facilitates efficient synthesis of pharmaceutical intermediates and API candidates.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H320-H335
Precautionary Statements : P264-P270-P330

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Computational Chemistry Data

TPSA 21.26
LogP 1.63
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Other aromatic heterocycles compounds

Key Words

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7-Fluoro-3,4-dihydro-2H-benzo[b][1,4]oxazine

CAS No. 56346-41-9

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