Tel:

Email:

EN
Cat. No. Size / Unit Price Qty
CS-W001157 4
Total: USD 88.00

3-Methylene-2-norbornanone,97% stabilized with MEHQ

  • CAS No. 5597-27-3

  • Cat. No. CS-0186844
  • Purity97% (stabilized with MEHQ)
  • MDL No.MFCD00151643

*For research and further manufacturing use only, not for direct human use.

3-Methylene-2-norbornanone,97% stabilized with MEHQ|CS-0186844

Structure of 5597-27-3

Please choose your location and provide accurate information for you
Size Stock
Price Quantity

* Please select Quantity before adding items.

General Information

  • CAS No. 5597-27-3
  • Cat. No. CS-0186844
  • Purity 97% (stabilized with MEHQ)
  • MDL No. MFCD00151643
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₁₀O
  • Molecular Weight 122.16
  • Synonym(s) 3-Methylenebicyclo[2.2.1]heptan-2-one
  • SMILES C=C1C2CCC(C2)C1=O

Description

3-Methylene-2-norbornanone, stabilized with MEHQ, is a reactive bicyclic ketone featuring a highly strained exocyclic methylene group. This bench-stable compound integrates readily into cycloaddition reactions and serves as a key intermediate in synthetic routes to complex polycyclic architectures.

Application

3-Methylene-2-norbornanone, stabilized with MEHQ, serves as a versatile bicyclic synthon in organic synthesis. Its strained norbornane framework and exocyclic methylene group enable efficient Diels-Alder reactions and functionalization at the 3-position. The compound exhibits good bench stability and facilitates access to complex carbocyclic architectures, making it valuable for medicinal chemistry and natural product synthesis workflows.

Synthesis

  • Route1
    • null|null
      74713-07-8
    • ~85%
    • In-stock
      3-Methylene-2-norbornanone,97% stabilized with MEHQ|CS-0186844
      5597-27-3

    References

    • Hon, Yung-Son; Hsu, Tzyy-Rong; Chen, Chun-Yan; Lin, Yi-Hui; Chang, Fong-Jong; Hsieh, Cheng-Han; Szu, Ping-Hui Tetrahedron, 2003 , vol. 59, # 9 p. 1509 - 1520
  • Route2
    • null|null
      5597-29-5
    • ~45%
    • In-stock
      3-Methylene-2-norbornanone,97% stabilized with MEHQ|CS-0186844
      5597-27-3

    References

    • Bowman, W. Russell; Brown, David S.; Burns, Catherine A.; Marples, Brian A.; Zaidi, Naveed A. Tetrahedron, 1992 , vol. 48, # 33 p. 6883 - 6896
  • Route3

    References

    • Tetrahedron, , vol. 59, # 9 p. 1509 - 1520

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02
Signal Word : Danger
UN#: 1224
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226
Precautionary Statements : P210-P233-P240-P241-P242-P243-P280-P370+P378-P501

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Computational Chemistry Data

  • TPSA   17.07
  • LogP   1.5416
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   0

Recently Viewed Products

Leave US a Message
Upload Pictures

Key Words

  • 5597-27-3 sigma5597-27-3 manufacturer5597-27-3 price5597-27-3 structure5597-27-3 SDSbuy 5597-27-35597-27-3 supplier5597-27-3 uses5597-27-3 molecular weightprice of 5597-27-35597-27-3 chemical name formula of 5597-27-3
This product is not sold in the region.
Confirm
How to get a Lot Number

Lot numbers can be found on the outside label of a product:

ChemScene Label