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CS-W001157 4
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Crystal violet, IND 0.0-2.0

  • CAS No. 548-62-9

  • Cat. No. CS-0169149
  • PurityIND
  • MDL No.MFCD00011750

*For research and further manufacturing use only, not for direct human use.

Crystal violet, IND 0.0-2.0|CS-0169149

Structure of 548-62-9

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General Information

  • CAS No. 548-62-9
  • Cat. No. CS-0169149
  • Purity IND
  • MDL No. MFCD00011750
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₅H₃₀ClN₃
  • Molecular Weight 407.98
  • Synonym(s) None
  • SMILES C/[N+](C)=C1C=C/C(C=C/1)=C(C2=CC=C(N(C)C)C=C2)\C3=CC=C(N(C)C)C=C3.[Cl-]

Description

Palladium(II)acetate, recrystallized, is commonly used as a catalyst in cross-coupling reactions. Prominent applications include the Buchwald-Hartwigamination reaction, Heck reaction, Suzuki coupling, Stille coupling, Sonogashira coupling, and Negishi coupling reactions.Palladium(II) acetate, recrystallized can be used as a catalyst:In Stille cross-coupling reaction between benzylic halides and aryl tributyltin to synthesize diarylmethane derivatives in the presence of phosphine ligand.For the -arylation of ketones with aryl halides to synthesize arylmethyl ketones in the presence of n-butylbis(1-adamantyl)-phosphine ligand.In Suzuki-Miyaura cross-coupling reaction between aryl bromides and aryl boronic acids to synthesize biaryl derivatives in the presence of phosphane ligand.In Buchwald-Hartwig amination reaction between aryl chlorides and anilines to synthesize arylated anilines in the presence of N-heterocyclic carbene ligand.

Synthesis

  • Route1
    • null|null
      121-69-7
    • In-stock
      p-Dimethylaminobenzaldehyde|CS-W020083
      100-10-7
    • ~86%
    • In-stock
      Crystal violet, IND 0.0-2.0|CS-0169149
      548-62-9

    References

    • Guzman-Lucero; Guzman; Likhatchev; Martinez-Palou Tetrahedron Letters, 2005 , vol. 46, # 7 p. 1119 - 1122
  • Route2

    References

    • DE27032 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 1, p. 77
  • Route3
    • null|null
      74497-02-2
    • In-stock
      Bis(4-(dimethylamino)phenyl)methanone|CS-W021001
      90-94-8
    • ~0%
    • Bis(4-(dimethylamino)phenyl)methanol|CS-0312713
      119-58-4
    • null|null
      26514-42-1
    • In-stock
      Crystal violet, IND 0.0-2.0|CS-0169149
      548-62-9

    References

    • Russian Journal of Organic Chemistry, , vol. 40, # 12 p. 1787 - 1790

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05,GHS07,GHS08,GHS09
Signal Word : Danger
UN#: 3077
Class : 9
Packing Group : Ⅲ
Hazard Statements : H302-H318-H351-H410
Precautionary Statements : P264-P270-P273-P280-P330-P391-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   9.49
  • LogP   1.4636
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   4

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