5-Bromo-1-methyl-1H-benzo[d]Imidazole

Name: 5-Bromo-1-methyl-1H-benzo[d]Imidazole
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 53484-15-4
Cat. No. CS-0036297
Purity≥96%
MDL No.MFCD09878409

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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5-Bromo-1-methyl-1H-benzo[d]Imidazole|CS-0036297

Structure of 53484-15-4

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General Information

CAS No. 53484-15-4
Cat. No. CS-0036297
Purity ≥96%
MDL No. MFCD09878409
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇BrN₂
Molecular Weight 211.06
Synonym(s) 5-Bromo-1-methylbenzimidazole
SMILES CN1C=NC2=C1C=CC(=C2)Br

Description

5-Bromo-1-methyl-1H-benzo[d]imidazole is a bench-stable heterocyclic compound featuring a bromine substituent at the 5-position and a methyl group at the nitrogen. This electron-deficient scaffold integrates readily into cross-coupling reactions, serving as a versatile building block for pharmaceutical intermediates and functional materials.

Application

5-Bromo-1-methyl-1H-benzo[d]imidazole serves as a versatile building block in medicinal chemistry and catalytic synthesis, enabling palladium-catalyzed cross-coupling reactions due to its stable bromo functionality. The methyl-substituted imidazole core offers enhanced solubility and bench stability, facilitating purification and scalability. Its compatibility with diverse reaction conditions makes it a reliable scaffold for constructing biologically relevant heterocycles and functionalized aromatic systems.

Synthesis

Route1
- 122-51-0
- In-stock
  
  69038-76-2
- ~%
- In-stock
  
  53484-15-4
References
- WO2003/99776 A1, ; Page 34-35 ;
Route2
- 64-18-6
- ~%
- In-stock
  
  53484-15-4
References
- Journal of the Chemical Society, , p. 2389,2393

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 17.82
LogP 2.3358
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Benzimidazole compounds

Key Words

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5-Bromo-1-methyl-1H-benzo[d]Imidazole

CAS No. 53484-15-4

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