(4-Mercaptophenyl)methanol

Name: (4-Mercaptophenyl)methanol
Brand: ChemScene
Availability: InStock
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CAS No. 53339-53-0
Cat. No. CS-0197752
Purity≥90%
MDL No.MFCD00041529

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 53339-53-0

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General Information

CAS No. 53339-53-0
Cat. No. CS-0197752
Purity ≥90%
MDL No. MFCD00041529
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈OS
Molecular Weight None
Synonym(s) 4-Mercaptobenzyl alcohol
SMILES C1=C(C=CC(=C1)S)CO

Description

(4-Mercaptophenyl)methanol features a phenyl ring bearing both a thiol and hydroxymethyl group in para configuration, enabling dual functionalization. This bifunctional scaffold integrates readily into conjugation workflows, offering robust anchoring points for bioconjugation and surface immobilization. The compound exhibits excellent stability under standard conditions and facilitates precise spatial control in molecular assembly.

Application

(4-Mercaptophenyl)methanol serves as a versatile building block for thioether and disulfide synthesis, enabling efficient functionalization in medicinal chemistry and materials science. Its dual functionality—thiol and primary alcohol—supports orthogonal transformations and facilitates conjugation strategies. The compound exhibits good bench stability and is readily purified by crystallization or column chromatography, making it well-suited for scalable synthetic workflows.

Synthesis

Route1
- In-stock
  
  1074-36-8
- ~67%
- In-stock
  
  53339-53-0
References
- Solingapuram Sai, Kiran Kumar; Kil, Kun-Eek; Tu, Zhude; Chu, Wenhua; Finck, Brian N.; Rothfuss, Justin M.; Shoghi, Kooresh I.; Welch, Michael J.; Gropler, Robert J.; Mach, Robert H. Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 19 p. 6233 - 6236
Route2
- In-stock
  
  18282-51-4
- ~89%
- In-stock
  
  53339-53-0
References
- Jiang, Yongwen; Qin, Yuxia; Xie, Siwei; Zhang, Xiaojing; Dong, Jinhua; Ma, Dawei Organic Letters, 2009 , vol. 11, # 22 p. 5250 - 5253
Route3
- 35190-68-2
- ~71%
- In-stock
  
  53339-53-0
References
- Itoh, Takahito; Gotoh, Kenji; Ishikawa, Noriyuki; Hamaguchi, Tosisige; Kubo, Masataka Journal of Organic Chemistry, 1996 , vol. 61, # 5 p. 1867 - 1869

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS05
Signal Word : Danger	UN#: 1759
Class : 8	Packing Group : Ⅲ
Hazard Statements : H318
Precautionary Statements : P280-P305+P351+P338-P310

Quality Control

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Computational Chemistry Data

TPSA 20.23
LogP 1.4676
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Mercaptan

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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(4-Mercaptophenyl)methanol

CAS No. 53339-53-0

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