Lot numbers can be found on the outside label of a product:
Picolinimidamide hydrochloride
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CAS No. 51285-26-8
- Cat. No. CS-0006839
- Purity≥95%
- MDL No.MFCD00052271
*For research and further manufacturing use only, not for direct human use.
Structure of 51285-26-8
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General Information
- CAS No. 51285-26-8
- Cat. No. CS-0006839
- Purity ≥95%
- MDL No. MFCD00052271
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₆H₈ClN₃
- Molecular Weight 157.60
- Synonym(s) Pyridine-2-carboximidamide hydrochloride
- SMILES N=C(C1=NC=CC=C1)N.Cl
Description
Picolinimidamide hydrochloride offers a robust, moisture-tolerant platform for imidamide-based ligand design. The protonated pyridine nitrogen enhances solubility and coordination stability, while the amidic functionality enables efficient coupling in transition-metal catalysis. This bench-stable derivative streamlines synthesis of chelating architectures in pharmaceutical and materials applications.
Application
Picolinimidamide hydrochloride serves as a versatile building block in synthetic organic chemistry, enabling efficient access to pyridine-containing heterocycles. Its imidamide functionality exhibits robust reactivity in nucleophilic substitution and cyclization reactions, particularly under mild conditions. The hydrochloride salt enhances solubility and bench stability, facilitating handling and purification in multi-step synthesis. Functions effectively in the construction of bioactive scaffolds, including those relevant to medicinal chemistry and agrochemical development.
Synthesis
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Route1
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In-stock
100-70-9 - ~72%
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In-stock
51285-26-8
References
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Zhang, Pengtao; Yang, Xinye; Zhang, Feiran; Gabelli, Sandra B.; Wang, Renxiao; Zhang, Yihua; Bhat, Shridhar; Chen, Xiaochun; Furlani, Manuel; Amzel, L. Mario; Liu, Jun O.; Ma, Dawei Bioorganic and Medicinal Chemistry, 2013 , vol. 21, # 9 p. 2600 - 2617
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Route2
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In-stock
19547-38-7 - ~%
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In-stock
51285-26-8
References
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Huixia, Xu; Yan, Yue; Litao, Qu; Yuying, Hao; Hua, Wang; Liuqing, Chen; Bingshe, Xu Dyes and Pigments, 2013 , vol. 99, # 1 p. 67 - 73
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Route3
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52313-50-5 - ~%
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In-stock
51285-26-8
References
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PHARMACIA CORPORATION Patent: WO2005/40133 A1, 2005 ; Location in patent: Page/Page column 126 ; WO 2005/040133 A1
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 62.76
- LogP 0.78747
- H_Acceptors 2
- H_Donors 2
- Rotatable_Bonds 1
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