3-Bromo-N-methylbenzamide

Name: 3-Bromo-N-methylbenzamide
Brand: ChemScene
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CAS No. 49834-22-2
Cat. No. CS-W020621
Purity≥95%
MDL No.MFCD01060879

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 49834-22-2
Cat. No. CS-W020621
Purity ≥95%
MDL No. MFCD01060879
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO
Molecular Weight 214.06
Synonym(s) Albb-009487
SMILES O=C(NC)C1=CC=CC(Br)=C1

Description

3-Bromo-N-methylbenzamide features a bromine atom at the meta position relative to the amide group, delivering enhanced electrophilicity for cross-coupling reactions. The N-methyl substitution improves solubility and reduces hydrogen-bonding interference, enabling efficient incorporation into complex molecular architectures under standard conditions.

Application

3-Bromo-N-methylbenzamide serves as a versatile building block in medicinal chemistry and synthetic organic chemistry, enabling direct functionalization at the aromatic ring and selective coupling reactions via the amide functionality. Its bromo group facilitates palladium-catalyzed cross-coupling, while the N-methylamide provides stability and compatibility with diverse reaction conditions. The compound exhibits excellent bench stability and ease of purification, making it well-suited for modular synthesis of bioactive heterocycles and pharmaceutical intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 29.1
LogP 1.8087
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-N-methylbenzamide

CAS No. 49834-22-2

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