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CS-W001157 4
Total: USD 88.00

((2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-(p-tolylthio)tetrahydro-2H-pyran-2-yl)methanol

  • CAS No. 479252-05-6

  • Cat. No. CS-0510840
  • Molecule weight556.71
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

((2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-(p-tolylthio)tetrahydro-2H-pyran-2-yl)methanol|CS-0510840

Structure of 479252-05-6

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General Information

  • CAS No. 479252-05-6
  • Cat. No. CS-0510840
  • Purity ≥98%
  • MDL No. None
  • Storage Sealed in dry,2-8℃
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₄H₃₆O₅S
  • Molecular Weight 556.71
  • Synonym(s) Tolyl 2,3,4-tri-O-benzyl-1-thio-beta-D-glucopyranoside, Thiocresyl 2,3,4-tri-O-benzyl-beta-D-glucopyranoside
  • SMILES OC[C@@H](O1)[C@@H](OCC2=CC=CC=C2)[C@H](OCC3=CC=CC=C3)[C@@H](OCC4=CC=CC=C4)[C@@H]1SC5=CC=C(C)C=C5

Synthesis

  • Route1
    • (4AR,6S,7R,8S,8aR)-7,8-bis(benzyloxy)-2-phenyl-6-(p-tolylthio)hexahydropyrano[3,2-d][1,3]dioxine|CS-0458971
      850416-39-6
    • ~93%
    • ((2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-(p-tolylthio)tetrahydro-2H-pyran-2-yl)methanol|CS-0510840
      479252-05-6

    References

    • Shie, Chi-Rung; Tzeng, Zheng-Hao; Wang, Cheng-Chung; Hung, Shang-Cheng Journal of the Chinese Chemical Society, 2009 , vol. 56, # 3 p. 510 - 523
  • Route2
    • null|null
      807361-70-2
    • ~85%
    • ((2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-(p-tolylthio)tetrahydro-2H-pyran-2-yl)methanol|CS-0510840
      479252-05-6

    References

    • Huang, Xuefei; Huang, Lijun; Wang, Haisheng; Ye, Xin-Shan Angewandte Chemie - International Edition, 2004 , vol. 43, # 39 p. 5221 - 5224
  • Route3
    • null|null
      762287-68-3
    • ~94%
    • ((2R,3R,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-(p-tolylthio)tetrahydro-2H-pyran-2-yl)methanol|CS-0510840
      479252-05-6

    References

    • France, Robert R.; Compton, Richard G.; Davis, Benjamin G.; Fairbanks, Antony J.; Rees, Neil V.; Wadhawan, Jay D. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 15 p. 2195 - 2202

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   57.15
  • LogP   6.56052
  • H_Acceptors   6
  • H_Donors   1
  • Rotatable_Bonds   12

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