4-Vinyl-1,3-dioxolan-2-one,98% (stabilized with MEHQ)

Name: 4-Vinyl-1,3-dioxolan-2-one,98% (stabilized with MEHQ)
Brand: ChemScene
Availability: InStock
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CAS No. 4427-96-7
Cat. No. CS-W011250
Purity98% (stabilized with MEHQ)
MDL No.MFCD00143315

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4-Vinyl-1,3-dioxolan-2-one,98% (stabilized with MEHQ)|CS-W011250

Structure of 4427-96-7

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General Information

CAS No. 4427-96-7
Cat. No. CS-W011250
Purity 98% (stabilized with MEHQ)
MDL No. MFCD00143315
Storage -20°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₆O₃
Molecular Weight 114.10
Synonym(s) Vinylethylene Carbonate
SMILES O=C1OCC(C=C)O1

Description

4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2. The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol. Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst.4-Vinyl-1,3-dioxolan-2-one may be used in the preparation of 2-arylbenzo[d]thiazole scaffolds.It may be used in the synthesis of the following multi-functional cyclic carbonates:4,4-((hexane-1,6-diylbis(sulfanediyl))bis-(ethane-2,1-diyl))bis(1,3-dioxolan-2-one) (Bis-CC)2-ethyl-2-(((3-((2-(2-oxo-1,3-dioxolan-4-yl)-ethyl)thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tris-CC)2,2-bis(((3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)-thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tetra-CC)

Synthesis

Route1
- 124-38-9
- In-stock
  
  2181-42-2
- 107-02-8
- ~63%
- In-stock
  
  4427-96-7
References
- Aher, Ravindra D.; Kumar, B. Senthil; Sudalai, Arumugam Synlett, 2014 , vol. 25, # 1 art. no. ST-2013-B0676-L, p. 97 - 101
Route2
- 930-22-3
- 124-38-9
- ~94%
- In-stock
  
  4427-96-7
References
- Li, Fuwei; Xia, Chungu; Xu, Liwen; Sun, Wei; Chen, Gexin Chemical Communications, 2003 , # 16 p. 2042 - 2043
Route3
- In-stock
  
  497-06-3
- 201230-82-2
- ~50%
- In-stock
  
  4427-96-7
References
- Pearson, David M.; Conley, Nicholas R.; Waymouth, Robert M. Advanced Synthesis and Catalysis, 2011 , vol. 353, # 16 p. 3007 - 3013

Safety Information

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GHS Pictogram :	GHS No : GHS06
Signal Word : Danger	UN#: 2810
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H301
Precautionary Statements : P264-P270-P330-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 35.53
LogP 0.7078
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Olefins

Material Science Polymer Materials Macromolecular Monomer

Building Blocks Skeleton Aliphatic heterocycle compounds Dioxolane compounds

Material Science Battery Materials Organic Solvents Carbonate Esters

Material Science Polymer/Macromolecule Reagents Monomers Vinyl Monomers

Material Science Electronic Materials Battery Materials Organic Solvents

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4-Vinyl-1,3-dioxolan-2-one,98% (stabilized with MEHQ)

CAS No. 4427-96-7

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