(E)-Hex-1-en-1-ylboronic acid

Name: (E)-Hex-1-en-1-ylboronic acid
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 42599-18-8
Cat. No. CS-0094491
Purity≥97%
MDL No.MFCD01074553

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(E)-Hex-1-en-1-ylboronic acid|CS-0094491

Structure of 42599-18-8

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Description

(E)-Hex-1-en-1-ylboronic acid features a conjugated vinyl boronic acid moiety enabling direct incorporation into Suzuki-Miyaura cross-coupling reactions. This bench-stable reagent delivers high functional group tolerance and stereoretention under standard conditions, streamlining access to substituted alkenes in synthetic workflows.

Application

(E)-Hex-1-en-1-ylboronic acid serves as a versatile building block in transition-metal-catalyzed coupling reactions, enabling efficient C–C bond formation via Suzuki-Miyaura protocols. The vinyl boronic acid functionality exhibits good bench stability and tolerates a range of functional groups, facilitating its use in the synthesis of conjugated systems and complex molecular architectures. Its defined (E)-stereochemistry ensures predictable reactivity and minimal side-product formation during cross-coupling.

General Information

CAS No. 42599-18-8
Cat. No. CS-0094491
Purity ≥97%
MDL No. MFCD01074553
Storage -20°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₃BO₂
Molecular Weight 127.98
Synonym(s) Hex-5-en-2-Ylboronic Acid
SMILES OB(/C=C/CCCC)O

Computational Chemistry Data

TPSA 40.46
LogP 0.7448
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 4

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P271-P280

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Other Classifications

Building Blocks Skeleton Fatty chain compounds

Key Words

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(E)-Hex-1-en-1-ylboronic acid

CAS No. 42599-18-8

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