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CS-W001157 4
Total: USD 88.00

Copper(I) trifluoromethanesulfonate benzene complex

  • CAS No. 42152-46-5

  • Cat. No. CS-0085305
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

Copper(I) trifluoromethanesulfonate benzene complex|CS-0085305

Structure of 42152-46-5

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General Information

  • CAS No. 42152-46-5
  • Cat. No. CS-0085305
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₆Cu₂F₆O₆S₂
  • Molecular Weight 503.33
  • Synonym(s) Trifluoromethanesulfonic Acid Copper(I) Salt Benzene Complex
  • SMILES O=S(O[Cu])(C(F)(F)F)=O.C1=CC=CC=C1

Description

Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst: To synthesize enol-esters via copper(I) carboxylate intermediate formation. In the enantioselective allylic oxidation of cyclic alkenes. To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation. It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic ,-unsaturated ketones, affording -alkylcarbonyls in high yield and with excellent enantioselectivity.

Safety Information

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GHS Pictogram :
GHS No : GHS02
Signal Word : Danger
UN#: 3175
Class : 4.1
Packing Group : Ⅱ
Hazard Statements : H228
Precautionary Statements : P210-P240-P241-P280-P370+P378

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Computational Chemistry Data

  • TPSA   43.37
  • LogP   2.001
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   1

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