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CS-W001157 4
Total: USD 88.00

Dimethyl acetonylphosphonate

  • CAS No. 4202-14-6

  • Cat. No. CS-D1401
  • Purity≥95%
  • MDL No.MFCD00008769

*For research and further manufacturing use only, not for direct human use.

Dimethyl acetonylphosphonate|CS-D1401

Structure of 4202-14-6

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General Information

  • CAS No. 4202-14-6
  • Cat. No. CS-D1401
  • Purity ≥95%
  • MDL No. MFCD00008769
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅H₁₁O₄P
  • Molecular Weight 166.11
  • Synonym(s) (Dimethylphosphono)acetone; Dimethyl (2-oxopropyl)phosphonate; Dimethyl acetylmethylphosphonate
  • SMILES CC(CP(OC)(OC)=O)=O

Description

Reagent used together with tosyl azide in a one-pot alkynylation of aldehydes.

Synthesis

  • Route1
    • null|null
      78-95-5
    • null|null
      121-45-9
    • ~69%
    • In-stock
      Dimethyl acetonylphosphonate|CS-D1401
      4202-14-6

    References

    • Sirivolu, Venkata Ramana; Vernekar, Sanjeev Kumar V.; Ilina, Tatiana; Myshakina, Nataliya S.; Parniak, Michael A.; Wang, Zhengqiang Journal of Medicinal Chemistry, 2013 , vol. 56, # 21 p. 8765 - 8780
  • Route2
    • null|null
      79-20-9
    • null|null
      756-79-6
    • ~57%
    • In-stock
      Dimethyl acetonylphosphonate|CS-D1401
      4202-14-6

    References

    • Yang, Hyeyeon; Hong, Young-Taek; Kim, Sunggak Organic Letters, 2007 , vol. 9, # 12 p. 2281 - 2284
  • Route3
    • null|null
      78-95-5
    • ~69%
    • In-stock
      Dimethyl acetonylphosphonate|CS-D1401
      4202-14-6

    References

    • Takasago International Corporation Patent: US5532402 A1, 1996 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   52.6
  • LogP   1.0613
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   4

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