(S)-(1,4-Dioxan-2-yl)methanol

Name: (S)-(1,4-Dioxan-2-yl)methanol
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CAS No. 406913-93-7
Cat. No. CS-0102180
Purity≥96%
MDL No.MFCD16652371

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(S)-(1,4-Dioxan-2-yl)methanol|CS-0102180

Structure of 406913-93-7

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General Information

CAS No. 406913-93-7
Cat. No. CS-0102180
Purity ≥96%
MDL No. MFCD16652371
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₁₀O₃
Molecular Weight 118.13
Synonym(s) Nantong Advanced Biomedical Technology Co., Ltd
SMILES OC[C@@H]1OCCOC1

Description

(S)-(1,4-Dioxan-2-yl)methanol is a chiral synthon featuring a hydroxymethyl group flanked by a rigid dioxane ring. This configuration enables stereocontrolled functionalization in asymmetric synthesis. The molecule combines structural stability with predictable reactivity, facilitating integration into complex molecular architectures under standard conditions.

Application

(S)-(1,4-Dioxan-2-yl)methanol serves as a chiral building block for stereoselective synthesis, offering a stable, bench-friendly platform for functionalization at the methylene position. Its 1,4-dioxane ring provides excellent solubility and compatibility with common coupling reactions, while the pendant hydroxyl group enables derivatization via esterification or ether formation. Functions effectively in multistep sequences requiring orthogonal reactivity and mild handling conditions.

Synthesis

Route1
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  406913-93-7
References
- Kim, Ha Young; Kuhn, Richard J.; Patkar, Chinmay; Warrier, Ranjit; Cushman, Mark Bioorganic and Medicinal Chemistry, 2007 , vol. 15, # 7 p. 2667 - 2679
Route2
- 406913-89-1
- ~%
- In-stock
  
  406913-93-7
References
- Pallavicini, Marco; Valoti, Ermanno; Villa, Luigi Enantiomer, 2001 , vol. 6, # 5 p. 267 - 273
Route3
- In-stock
  
  29908-11-0
- ~%
- In-stock
  
  406913-93-7
References
- Pallavicini, Marco; Valoti, Ermanno; Villa, Luigi Enantiomer, 2001 , vol. 6, # 5 p. 267 - 273

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 38.69
LogP -0.6059
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Building Blocks Skeleton Aliphatic heterocycle compounds Other aliphatic heterocycles compounds

Key Words

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(S)-(1,4-Dioxan-2-yl)methanol

CAS No. 406913-93-7

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