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CS-W001157 4
Total: USD 88.00

Methyl diphenylphosphinite

  • CAS No. 4020-99-9

  • Cat. No. CS-0085666
  • Purity≥95%
  • MDL No.MFCD00048025

*For research and further manufacturing use only, not for direct human use.

Methyl diphenylphosphinite|CS-0085666

Structure of 4020-99-9

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General Information

  • CAS No. 4020-99-9
  • Cat. No. CS-0085666
  • Purity ≥95%
  • MDL No. MFCD00048025
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₃H₁₃OP
  • Molecular Weight 216.22
  • Synonym(s) Methoxydiphenylphosphine
  • SMILES COP(C1=CC=CC=C1)C2=CC=CC=C2

Description

Ased as:Catalyst for hydroformylative desymmetrization of bisalkenyl carbinols and bishomoallylic carbinolsLigand in rhodium-catalyzed hydroformylation of bishomoallylic alcoholsCalatyst in preparation of -lactones via branched-regioselective hydroformylation reactionsLigand for nickel-catalyzed hydrocyanation reactionsCatalyst in annulation reactions

Synthesis

  • Route1
    • null|null
      67-56-1
    • null|null
      1079-66-9
    • ~85%
    • In-stock
      Methyl diphenylphosphinite|CS-0085666
      4020-99-9

    References

    • Gruenanger, Christian U.; Breit, Bernhard Angewandte Chemie - International Edition, 2008 , vol. 47, # 38 p. 7346 - 7349
  • Route2
    • null|null
      1079-66-9
    • ~71%
    • In-stock
      Methyl diphenylphosphinite|CS-0085666
      4020-99-9

    References

    • Hoechst Aktiengesellschaft Patent: US5705669 A1, 1998 ;
  • Route3
    • null|null
      54877-59-7
    • ~%
    • In-stock
      Methyl diphenylphosphinite|CS-0085666
      4020-99-9

    References

    • Dabkowski, Wojciech; Michalski, Jan; Skrzypczynski, Zbigniew Journal of the Chemical Society, Chemical Communications, 1982 , # 21 p. 1260 - 1261

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS06
Signal Word : Danger
UN#: 2810
Class : 6.1
Packing Group : Ⅲ
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   9.23
  • LogP   2.6807
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   3

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