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CS-W001157 4
Total: USD 88.00

1-(Trifluoromethyl)-4-vinylbenzene,98% (stabilized with TBC)

  • CAS No. 402-50-6

  • Cat. No. CS-0040742
  • Purity97% (stabilized with TBC)
  • MDL No.MFCD00075539

*For research and further manufacturing use only, not for direct human use.

1-(Trifluoromethyl)-4-vinylbenzene,98% (stabilized with TBC)|CS-0040742

Structure of 402-50-6

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General Information

  • CAS No. 402-50-6
  • Cat. No. CS-0040742
  • Purity 97% (stabilized with TBC)
  • MDL No. MFCD00075539
  • Storage -20°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₇F₃
  • Molecular Weight 172.15
  • Synonym(s) 4-(Trifluoromethyl)styrene
  • SMILES FC(C1=CC=C(C=C)C=C1)(F)F

Description

1-(Trifluoromethyl)-4-vinylbenzene, stabilized with TBC, features a trifluoromethyl group that imparts strong electron-withdrawing character and enhanced stability. The vinyl functionality enables efficient copolymerization in radical-mediated reactions. This bench-stable monomer combines high reactivity with moisture tolerance, making it ideal for precision synthesis in advanced polymer systems and functional materials development.

Application

1-(Trifluoromethyl)-4-vinylbenzene, stabilized with TBC, serves as a versatile building block for conjugated polymers and functionalized aromatic systems. Its vinyl group enables efficient Diels-Alder, cross-coupling, and radical polymerization reactions, while the trifluoromethyl moiety imparts enhanced lipophilicity and metabolic stability. The compound exhibits excellent bench stability and facilitates straightforward purification, making it ideal for applications in materials science and medicinal chemistry.

Synthesis

  • Route1

    References

    • Bosiak, Mariusz J.; Rakowiecki, Marcin; Orlowska, Katarzyna J.; Kedziera, Dariusz; Adams, Joerg Dyes and Pigments, 2013 , vol. 99, # 3 p. 803 - 811
  • Route2

    References

    • Abdel-Baky, Samy; Moussa, Adel Synthetic Communications, 1988 , vol. 18, # 15 p. 1795 - 1800
  • Route3
    • In-stock
      4-Iodobenzotrifluoride|CS-W004060
      455-13-0
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      78599-06-1
    • ~88%
    • In-stock
      1-(Trifluoromethyl)-4-vinylbenzene,98% (stabilized with TBC)|CS-0040742
      402-50-6

    References

    • Hosoi, Kazushi; Nozaki, Kyoko; Hiyama, Tamejiro Chemistry Letters, 2002 , # 2 p. 138 - 139

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Danger
UN#: 1993
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226-H315-H319-H335
Precautionary Statements : P210-P233-P240-P241-P242-P243-P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.3484
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   1

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