2-Hydroxy-5-methylbenzamide

Name: 2-Hydroxy-5-methylbenzamide
Brand: ChemScene
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CAS No. 39506-61-1
Cat. No. CS-0179654
Purity≥96%
MDL No.MFCD00017124

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Type	HazMat Fee
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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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General Information

CAS No. 39506-61-1
Cat. No. CS-0179654
Purity ≥96%
MDL No. MFCD00017124
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₉NO₂
Molecular Weight 151.16
Synonym(s) 5-MethylSalicylamide
SMILES O=C(N)C1=CC(C)=CC=C1O

Description

2-Hydroxy-5-methylbenzamide features a phenolic hydroxyl and amide functional group ortho to a methyl substituent, enabling directional hydrogen bonding and enhanced solubility in polar solvents. This structural motif supports integration into bioactive scaffolds and serves as a key intermediate in pharmaceutical synthesis.

Application

2-Hydroxy-5-methylbenzamide serves as a versatile building block in medicinal chemistry, enabling the synthesis of bioactive heterocycles and pharmaceutical intermediates. Its ortho-hydroxyl and amide functionalities offer directed metalation and hydrogen bonding potential, while the methyl group provides a handle for further functionalization. The compound exhibits good bench stability and is compatible with standard coupling and cyclization protocols, facilitating efficient access to complex scaffolds in API development workflows.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 63.32
LogP 0.79952
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Hydroxy-5-methylbenzamide

CAS No. 39506-61-1

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