2-(Prop-1-en-2-yl)naphthalene

Name: 2-(Prop-1-en-2-yl)naphthalene
Brand: ChemScene
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CAS No. 3710-23-4
Cat. No. CS-0182190
Purity≥95%
MDL No.MFCD00191524

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-(Prop-1-en-2-yl)naphthalene|CS-0182190

Structure of 3710-23-4

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General Information

CAS No. 3710-23-4
Cat. No. CS-0182190
Purity ≥95%
MDL No. MFCD00191524
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₃H₁₂
Molecular Weight 168.23
Synonym(s) 2-Isopropenylnaphthalene
SMILES C=C(C1=CC=C2C=CC=CC2=C1)C

Description

2-(Prop-1-en-2-yl)naphthalene features a conjugated vinyl group attached directly to the naphthalene core, enabling efficient integration into Diels-Alder cycloadditions and other pericyclic reactions. The electron-rich aromatic system enhances reactivity in transition-metal-catalyzed coupling processes. This compound exhibits high thermal stability and is readily handled under standard laboratory conditions.

Application

2-(Prop-1-en-2-yl)naphthalene serves as a versatile building block in synthetic organic chemistry, enabling efficient access to functionalized naphthalene derivatives via electrophilic addition and transition-metal-catalyzed coupling reactions. The exocyclic ene group exhibits high reactivity in Diels–Alder processes and allows for selective functionalization under mild conditions. Its bench-stable nature and compatibility with common protecting groups facilitate straightforward purification and integration into complex molecular architectures, making it a practical scaffold for medicinal chemistry and materials synthesis workflows.

Synthesis

Route1
- 904744-26-9
- ~78%
- In-stock
  
  3710-23-4
References
- Lin, Ming-Yuan; Das, Arindam; Liu, Rai-Shung Journal of the American Chemical Society, 2006 , vol. 128, # 29 p. 9340 - 9341
Route2
- 335331-53-8
- ~87%
- In-stock
  
  3710-23-4
References
- Matsuda, Takanori; Shigeno, Masanori; Murakami, Masahiro Chemistry Letters, 2006 , vol. 35, # 3 p. 288 - 289
Route3
- In-stock
  
  20351-54-6
- ~97%
- In-stock
  
  3710-23-4
References
- Matsumoto; Takeda; Iwata; Sakamoto; Ishida Chemical and Pharmaceutical Bulletin, 1994 , vol. 42, # 6 p. 1191 - 1197

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS08,GHS09
Signal Word : Danger	UN#: 3077
Class : 9	Packing Group : Ⅲ
Hazard Statements : H302-H361-H372-H410
Precautionary Statements : P264-P280-P301+P330+P331

Quality Control

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Computational Chemistry Data

TPSA 0
LogP 3.8729
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Skeleton Aromatic ring compounds Naphthalene compounds

Key Words

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2-(Prop-1-en-2-yl)naphthalene

CAS No. 3710-23-4

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