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CS-W001157 4
Total: USD 88.00

(S,S)-DIOP

  • CAS No. 37002-48-5

  • Cat. No. CS-W011503
  • Purity≥95%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(S,S)-DIOP|CS-W011503

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General Information

  • CAS No. 37002-48-5
  • Cat. No. CS-W011503
  • Purity ≥95%
  • MDL No. None
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₁H₃₂O₂P₂
  • Molecular Weight 498.54
  • Synonym(s) T5O COTJ B1 B1 D1PR&R& E1PR&R &&(4S,5S)-(+)- Form [WLN]
  • SMILES CC(O1)(C)O[C@H](CP(C2=CC=CC=C2)C3=CC=CC=C3)[C@H]1CP(C4=CC=CC=C4)C5=CC=CC=C5

Description

(S,S)-DIOP delivers high enantioselectivity in asymmetric catalysis, featuring a rigid chiral backbone that stabilizes transition states through defined spatial orientation. This diphosphine ligand integrates effectively into palladium and rhodium complexes, enabling precise control in cross-coupling and hydrogenation reactions under standard conditions.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   5.7723
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   8

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