3-Bromo-4-hydroxypyridine

Name: 3-Bromo-4-hydroxypyridine
Brand: ChemScene
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CAS No. 36953-41-0
Cat. No. CS-D0895
Purity≥96%
MDL No.MFCD01646107

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 36953-41-0
Cat. No. CS-D0895
Purity ≥96%
MDL No. MFCD01646107
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₄BrNO
Molecular Weight 174.00
Synonym(s) None
SMILES OC1=C(Br)C=NC=C1

Description

3-Bromo-4-hydroxypyridine is a functionalized heterocycle featuring a bromine atom at the 3-position and a hydroxyl group at the 4-position, enabling selective derivatization. This arrangement supports efficient cross-coupling reactions and facilitates incorporation into bioactive scaffolds. The compound exhibits favorable stability under standard handling conditions and serves as a key intermediate in the synthesis of pharmaceutical candidates and advanced ligands.

Application

3-Bromo-4-hydroxypyridine serves as a versatile building block for the synthesis of functionalized pyridine derivatives, enabling direct substitution at the bromine site via palladium-catalyzed cross-coupling reactions. The hydroxyl group provides a handle for derivatization or protection, offering orthogonal reactivity in multi-step syntheses. Its bench-stable nature and compatibility with standard reaction conditions make it suitable for medicinal chemistry and process development workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 33.12
LogP 1.5497
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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3-Bromo-4-hydroxypyridine

CAS No. 36953-41-0

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