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CS-W001157 4
Total: USD 88.00

4,4,5,5-Tetramethyl-2-(4-methylbenzyl)-1,3,2-dioxaborolane

  • CAS No. 356570-52-0

  • Cat. No. CS-0061305
  • Molecule weight232.13
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

4,4,5,5-Tetramethyl-2-(4-methylbenzyl)-1,3,2-dioxaborolane|CS-0061305

Structure of 356570-52-0

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General Information

  • CAS No. 356570-52-0
  • Cat. No. CS-0061305
  • Purity ≥97%
  • MDL No. None
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₄H₂₁BO₂
  • Molecular Weight 232.13
  • Synonym(s) 4-Methylbenzylboronic acid pinacol ester
  • SMILES CC1=CC=C(C=C1)CB2OC(C)(C)C(C)(C)O2

Synthesis

  • Route1
    • null|null
      104-81-4
    • null|null
      25015-63-8
    • ~92%
    • In-stock
      4,4,5,5-Tetramethyl-2-(4-methylbenzyl)-1,3,2-dioxaborolane|CS-0061305
      356570-52-0

    References

    • Pintaric, Christine; Olivero, Sandra; Gimbert, Yves; Chavant, Pierre Y.; Dunach, Elisabet Journal of the American Chemical Society, 2010 , vol. 132, # 34 p. 11825 - 11827
  • Route2
    • null|null
      106-38-7
    • In-stock
      Bis[(pinacolato)boryl]methane|CS-0153823
      78782-17-9
    • ~92%
    • In-stock
      4,4,5,5-Tetramethyl-2-(4-methylbenzyl)-1,3,2-dioxaborolane|CS-0061305
      356570-52-0

    References

    • Endo, Kohei; Ohkubo, Takahiro; Shibata, Takanori Organic Letters, 2011 , vol. 13, # 13 p. 3368 - 3371
  • Route3
    • null|null
      104-82-5
    • In-stock
      Bis(pinacolato)diborane|CS-D1216
      73183-34-3
    • ~79%
    • In-stock
      4,4,5,5-Tetramethyl-2-(4-methylbenzyl)-1,3,2-dioxaborolane|CS-0061305
      356570-52-0

    References

    • Giroux, Andre Tetrahedron Letters, 2003 , vol. 44, # 2 p. 233 - 235

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   3.16892
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   2

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