Methyl 3-Hydroxy-4-methylbenzoate

Name: Methyl 3-Hydroxy-4-methylbenzoate
Brand: ChemScene
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CAS No. 3556-86-3
Cat. No. CS-0099370
Purity≥98%
MDL No.MFCD00213808

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 3-Hydroxy-4-methylbenzoate|CS-0099370

Structure of 3556-86-3

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Description

Methyl 3-hydroxy-4-methylbenzoate features a hydroxyl group ortho to the ester and a methyl substituent at the para position, enabling selective derivatization in synthetic sequences. This electron-rich aromatic scaffold supports efficient coupling reactions under mild conditions and exhibits enhanced solubility in polar organic solvents.

Application

Methyl 3-hydroxy-4-methylbenzoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted benzoic acid derivatives and heterocyclic scaffolds. The ortho-hydroxyl and methyl groups provide complementary sites for selective functionalization, while the ester moiety supports transformations such as hydrolysis, reduction, or coupling reactions. Bench-stable and amenable to standard purification techniques, it facilitates reliable downstream synthesis in medicinal chemistry and materials development.

General Information

CAS No. 3556-86-3
Cat. No. CS-0099370
Purity ≥98%
MDL No. MFCD00213808
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₁₀O₃
Molecular Weight 166.17
Synonym(s) 3-hydroxy-4-methylbenzoate
SMILES O=C(C1=CC=C(C(O)=C1)C)OC

Computational Chemistry Data

TPSA 46.53
LogP 1.48722
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P302+P352-P304+P340

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 3-Hydroxy-4-methylbenzoate

CAS No. 3556-86-3

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