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CS-W001157 4
Total: USD 88.00

(2-(4-Bromophenyl)ethene-1,1,2-triyl)tribenzene

  • CAS No. 34699-28-0

  • Cat. No. CS-W018438
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(2-(4-Bromophenyl)ethene-1,1,2-triyl)tribenzene|CS-W018438

Structure of 34699-28-0

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General Information

  • CAS No. 34699-28-0
  • Cat. No. CS-W018438
  • Purity ≥97%
  • MDL No. None
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₆H₁₉Br
  • Molecular Weight 411.33
  • Synonym(s) 1-Bromo-4-(1,2,2-triphenylethenyl)benzene
  • SMILES BrC1=CC=C(C(C2=CC=CC=C2)=C(C3=CC=CC=C3)C4=CC=CC=C4)C=C1

Description

This tribenzene derivative features a (2-(4-bromophenyl)ethene-1,1,2-triyl) core that integrates three benzene rings through conjugated vinyl linkages. The pendant bromophenyl group enables facile cross-coupling reactions, while the extended π-system enhances electronic delocalization. Designed for precision synthesis in organic electronics and advanced materials, this molecule offers robust structural integrity under standard reaction conditions.

Application

(2-(4-Bromophenyl)ethene-1,1,2-triyl)tribenzene serves as a versatile multi-functional building block for palladium-catalyzed cross-coupling reactions, enabling the construction of complex polycyclic architectures. Its brominated aryl group facilitates reliable Suzuki-Miyaura and Stille couplings, while the triaryl ethylene core provides structural rigidity and enhanced stability under standard reaction conditions. The molecule exhibits excellent bench stability and clean purification profiles, making it well-suited for iterative synthesis in medicinal chemistry and materials science applications.

Synthesis

  • Route1

    References

    • Tsvelikhovsky, Dmitry; Blum, Jochanan European Journal of Organic Chemistry, 2008 , # 14 p. 2417 - 2422
  • Route2

    References

    • Zhang, Xiqi; Chi, Zhenguo; Li, Haiyin; Xu, Bingjia; Li, Xiaofang; Liu, Siwei; Zhang, Yi; Xu, Jiarui Journal of Materials Chemistry, 2011 , vol. 21, # 6 p. 1788 - 1796 Title/Abstract Full Text View citing articles Show Details Zhang, Xiqi; Chi, Zhenguo; Xu, Bingjia; Chen, Chengjian; Zhou, Xie; Zhang, Yi; Liu, Siwei; Xu, Jiarui Journal of Materials Chemistry, 2012 , vol. 22, # 35 p. 18505 - 18513
  • Route3

    References

    • Zhang, Xiqi; Chi, Zhenguo; Li, Haiyin; Xu, Bingjia; Li, Xiaofang; Liu, Siwei; Zhang, Yi; Xu, Jiarui Journal of Materials Chemistry, 2011 , vol. 21, # 6 p. 1788 - 1796 Title/Abstract Full Text View citing articles Show Details Zhang, Xiqi; Chi, Zhenguo; Xu, Bingjia; Chen, Chengjian; Zhou, Xie; Zhang, Yi; Liu, Siwei; Xu, Jiarui Journal of Materials Chemistry, 2012 , vol. 22, # 35 p. 18505 - 18513

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   7.4565
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   4

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