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CS-W001157 4
Total: USD 88.00

DiethylDiallylmalonate,98% (stabilized with MEHQ)

  • CAS No. 3195-24-2

  • Cat. No. CS-0167979
  • Purity98% (stabilized with MEHQ)
  • MDL No.MFCD00009126

*For research and further manufacturing use only, not for direct human use.

DiethylDiallylmalonate,98% (stabilized with MEHQ)|CS-0167979

Structure of 3195-24-2

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General Information

  • CAS No. 3195-24-2
  • Cat. No. CS-0167979
  • Purity 98% (stabilized with MEHQ)
  • MDL No. MFCD00009126
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₃H₂₀O₄
  • Molecular Weight 240.30
  • Synonym(s) diethyl diprop-2-en-1-ylpropanedioate
  • SMILES O=C(OCC)C(CC=C)(CC=C)C(OCC)=O

Description

Low catalyst loading in ring-closing metathesis reaction of diethyl diallylmalonate has been reported. Cationic nickel (with monodentate phosphoramidites and Wilkes azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Synthesis

  • Route1
    • null|null
      106-95-6
    • null|null
      105-53-3
    • ~97%
    • In-stock
      DiethylDiallylmalonate,98% (stabilized with MEHQ)|CS-0167979
      3195-24-2

    References

    • Bouzbouz, Samir; Boulard, Lucie; Cossy, Janine Organic Letters, 2007 , vol. 9, # 19 p. 3765 - 3768
  • Route2
    • In-stock
      Diethyl allylmalonate,97%(stabilized with MEHQ)|CS-0011112
      2049-80-1
    • null|null
      106-95-6
    • ~89%
    • In-stock
      DiethylDiallylmalonate,98% (stabilized with MEHQ)|CS-0167979
      3195-24-2

    References

    • Bouhadir, Kamal H.; Zhou, Jing-Lan; Shevlin, Philip B. Synthetic Communications, 2005 , vol. 35, # 7 p. 1003 - 1010
  • Route3
    • null|null
      591-87-7
    • null|null
      105-53-3
    • ~15%
    • In-stock
      Diethyl allylmalonate,97%(stabilized with MEHQ)|CS-0011112
      2049-80-1
    • In-stock
      DiethylDiallylmalonate,98% (stabilized with MEHQ)|CS-0167979
      3195-24-2

    References

    • Tetrahedron Letters, , vol. 25, # 39 p. 4379 - 4382

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   52.6
  • LogP   2.2512
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   8

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