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CS-W001157 4
Total: USD 88.00

Diaza-15-crown-5

  • CAS No. 31249-95-3

  • Cat. No. CS-0155187
  • Purity≥96%
  • MDL No.MFCD00005109

*For research and further manufacturing use only, not for direct human use.

Diaza-15-crown-5|CS-0155187

Structure of 31249-95-3

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General Information

  • CAS No. 31249-95-3
  • Cat. No. CS-0155187
  • Purity ≥96%
  • MDL No. MFCD00005109
  • Storage 4°C, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₂₂N₂O₃
  • Molecular Weight 218.29
  • Synonym(s) None
  • SMILES C1COCCNCCOCCOCCN1

Description

Diaza-15-crown-5 features a macrocyclic ether framework with two nitrogen atoms integrated into the ring, enhancing its affinity for alkali metal cations. This structure enables selective coordination in complexation chemistry, particularly useful in supramolecular systems and ion transport studies under standard conditions.

Application

Diaza-15-crown-5 serves as a selective ligand for alkali metal ions, particularly potassium and sodium, leveraging its macrocyclic cavity and dual nitrogen donors to enable efficient complexation in polar solvents. Its bench-stable, crystalline nature facilitates straightforward handling and purification, while the azo-functionalized backbone enhances solubility and compatibility with common organic synthesis workflows. Functions effectively in ion transport studies and as a template for metal-directed assembly reactions.

Synthesis

  • Route1
    • null|null
      94195-16-1
    • ~90%
    • In-stock
      Diaza-15-crown-5|CS-0155187
      31249-95-3

    References

    • Gatto, Vincent J.; Arnold, Kristin A.; Viscariello, Anthony M.; Miller, Steven R.; Morgan, Charles R.; Gokel, George W. Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5373 - 5384
  • Route2
    • null|null
      30989-20-9
    • ~83%
    • In-stock
      Diaza-15-crown-5|CS-0155187
      31249-95-3

    References

    • Jurczak, Janusz; Kasprzyk, Stanislaw; Salanski, Piotr; Stankiewicz, Tomasz Journal of the Chemical Society, Chemical Communications, 1991 , # 14 p. 956 - 957
  • Route3
    • 7,13-Ditosyl-1,4,10-trioxa-7,13-diazacyclopentadecane|CS-0541088
      74461-33-9
    • ~85%
    • In-stock
      Diaza-15-crown-5|CS-0155187
      31249-95-3

    References

    • Luk'yanenko, N.G.; Basok, S.S.; Filonova, L.K. Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, p. 1562 - 1571 Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 8 p. 1731 - 1742

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

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Computational Chemistry Data

  • TPSA   51.75
  • LogP   -0.771
  • H_Acceptors   5
  • H_Donors   2
  • Rotatable_Bonds   0

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