5,6-Dimethyl-1,10-phenanthroline

Name: 5,6-Dimethyl-1,10-phenanthroline
Brand: ChemScene
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CAS No. 3002-81-1
Cat. No. CS-W004561
Purity≥96%
MDL No.MFCD00004983

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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5,6-Dimethyl-1,10-phenanthroline|CS-W004561

Structure of 3002-81-1

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General Information

CAS No. 3002-81-1
Cat. No. CS-W004561
Purity ≥96%
MDL No. MFCD00004983
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₄H₁₂N₂
Molecular Weight 208.26
Synonym(s) 5 6-DIMETHYL-1,10-PHENANTHROLINE ACS
SMILES CC1=C(C=CC=N2)C2=C(N=CC=C3)C3=C1C

Description

5,6-Dimethyl-1,10-phenanthroline was employed as ligand in the preparation of:novel tetrahedral copper(I) mixed-ligand complexesmixed ligand Ru(II) complexes5,6-bis(bromomethyl)-1,10-phenanthroline via bromination with N-bromosuccinimide

Application

5,6-Dimethyl-1,10-phenanthroline serves as a sterically tuned bidentate ligand in transition metal catalysis, enhancing complex stability and selectivity in cross-coupling and oxidation reactions. Its methylated peri-positions improve solubility and bench stability while maintaining strong metal coordination. The compound facilitates efficient catalyst turnover in Pd- and Cu-mediated transformations and is particularly valuable for constructing heterocyclic scaffolds under mild conditions.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 25.78
LogP 3.39984
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

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5,6-Dimethyl-1,10-phenanthroline

CAS No. 3002-81-1

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